ETM | 54902-90-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: ETM
• 英文别名: Ethylentetramethanol；2,3-bis-hydroxymethyl-but-2-ene-1,4-diol；Tetra(hydroxymethyl)ethene；2,3-bis(hydroxymethyl)but-2-ene-1,4-diol
• CAS: 54902-90-8
• 化学式: C₆H₁₂O₄
• 分子量: 148.159
• InChiKey: JVEKMZVMJIFLEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.1
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  80.9
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-溴代庚烷 、 ETM 在 sodium hydroxide 、 四丁基溴化铵 作用下， 生成 1-(4-Heptyloxy-2,3-bis-heptyloxymethyl-but-2-enyloxy)-heptane
  参考文献：
  名称：

  Alkylation of pentaerythritol by phase-transfer catalysis. 3. Influence of the tetrahedral structure of pentaerythritol on the rate and selectivity of the phase-transfer-catalyzed reaction

  摘要：

  DOI：

  10.1021/jo00390a008
• 作为产物：
  描述：

  2,2,2,',2'-tetramethyl-5,5'-dinitro-5,5'-bi(1,3-dioxane) 在 sodium sulfide 、 氢气 作用下， 以 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 生成 ETM
  参考文献：
  名称：

  反应S RN 1在杂环上：IV：在二甲基-2,2硝基-5二恶烷-1,3中重新活化

  摘要：

  通过S RN 1反应与2,2-二甲基5-硝基1,3的盐制备2-烷基2-硝基1,3-丙二醇，2-亚烷基1,3-丙二醇和2-二亚烷基1,3-丙二醇-二恶烷和酸催化裂解所产生的缩醛。

  DOI：

  10.1016/s0040-4039(00)98882-8

文献信息

• Carrier for immobilizing microorganisms, and method for converting nitrogen compounds in a liquid using the same
  申请人：Matsumura, Masatoshi

  公开号：EP0758680A2

  公开（公告）日：1997-02-19

  A carrier for immobilizing microorganisms, comprising a porous cellulose derivative or a porous cellulose, which has a good affinity for the microorganisms, can be applied to any liquid treatment tank without limiting use sites, and does not require a plant investment for immobilization of the microorganisms, and a method of converting nitrogen compounds in a liquid to be treated such as potable water or wastewater, by introducing the carrier together with the liquid to be treated into a liquid treatment tank such as a nitrification treatment tank or a denitrification treatment tank, thereby converting the nitrogen compounds contained in the liquid to be treated into harmless nitrogen compounds, are disclosed.

  一种固定微生物的载体，由多孔纤维素衍生物或多孔纤维素组成，对微生物具有良好的亲和力，可应用于任何液体处理池而不限制使用地点，并且不需要为固定微生物而投资建厂、本发明还公开了一种将饮用水或废水等待处理液体中的氮化合物转化为无害氮化合物的方法，方法是将载体与待处理液体一起引入硝化处理池或反硝化处理池等液体处理池，从而将待处理液体中所含的氮化合物转化为无害氮化合物。
• NOUGUIER R. M.; MCHICH M., J. ORG. CHEM., 52,(1987) N 14, 2995-2997
  作者：NOUGUIER R. M.、 MCHICH M.

  DOI：——

  日期：——
• AUTOINDUCER COMPOUND TO IMPROVE THE PRODUCTIVITY OF NATAMYCIN PRODUCING STREPTOMYCES STRAINS
  申请人：DSM IP Assets B.V.

  公开号：EP1625225A1

  公开（公告）日：2006-02-15
• Autoinducer compound to improve the productivity of natamycin streptomyces strains
  申请人：Recio Perez Eliseo

  公开号：US20060275873A1

  公开（公告）日：2006-12-07

  The invention provides a compound of the formula (I). Furthermore, the invention provides a process for the production of a compound of formula (I). The present invention also provides a process for the production of natamycin by a Streptomyces strain comprising adding a composition comprising an auto inducer to the fermentation medium. The present invention furthermore provides the use of a compound of formula (I) in the manufacture of a product by fermentation of a Streptomyces strain. The present invention finally discloses a Streptomyces strain that is defective in natamycin production and that is capable of producing a compound of formula (I) wherein both R 1 and R 2 are hydrogen and a Streptomyces strain that is defective in production of a compound of formula (I) wherein both R 1 and R 2 are hydrogen and that is capable of producing natamycin in the presence of said compound.
• US5935844A
  申请人：——

  公开号：US5935844A

  公开（公告）日：1999-08-10