2,6,6-trimethylcyclohept-4-en-1-one | 35836-98-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2,6,6-trimethylcyclohept-4-en-1-one
• 英文别名: α-Dihydroeucarvon；(+/-)-2,6,6-trimethyl-cyclohept-4-enone; (+/-)-α-dihydroeucarvone；(+/-)-1.1.4-Trimethyl-cyclohepten-(5)-on-(3)；(+/-)-2,6,6-Trimethyl-cyclohept-4-enon; (+/-)-α-Dihydroeucarvon；2,6,6-Trimethyl-cyclohept-4-enon；2,6,6-Trimethylcyclohept-4-en-1-one
• CAS: 35836-98-7
• 化学式: C₁₀H₁₆O
• 分子量: 152.236
• InChiKey: SUYHURBXNJBHSV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  优葛缕酮 在 1,4-dihydronicotinamide adenine dinucleotide 、 Triton X-100 作用下， 反应 24.0h， 生成 2,6,6-trimethylcyclohept-4-en-1-one
  参考文献：
  名称：

  Characterization of two enone reductases from Nicotiana tabacum cell cultures

  摘要：

  Two enone reductases, designated Reductase-I and -II, were isolated from Nicotiana tabacum cell cultures. These two reductases have different M(r)s, pH optimum, coenzyme requirement and substrate specificity. Reductase-I catalyses the reduction of the endocyclic C-C double bond of enones which bear a hydrogen-substituent at the position beta to the carbonyl, while Reductase-II catalyses the reduction of the exocyclic C-C double bond of enones.

  DOI：

  10.1016/0031-9422(92)83593-n

文献信息

• Characterization of two enone reductases from Nicotiana tabacum cell cultures
  作者：Yi-xiong Tang、Takayuki Suga

  DOI：10.1016/0031-9422(92)83593-n

  日期：1992.8

  Two enone reductases, designated Reductase-I and -II, were isolated from Nicotiana tabacum cell cultures. These two reductases have different M(r)s, pH optimum, coenzyme requirement and substrate specificity. Reductase-I catalyses the reduction of the endocyclic C-C double bond of enones which bear a hydrogen-substituent at the position beta to the carbonyl, while Reductase-II catalyses the reduction of the exocyclic C-C double bond of enones.