1-tert-butyl-3-methylcyclopentadiene | 150295-91-3

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 1-tert-butyl-3-methylcyclopentadiene
• 英文别名: 2-methyl-4-t-butyl-cyclopentadiene；1-Tert-butyl-3-methylcyclopenta-1,3-diene
• CAS: 150295-91-3
• 化学式: C₁₀H₁₆
• mdl: MFCD12546361
• 分子量: 136.237
• InChiKey: DEOPMCBOUWSRHC-UHFFFAOYSA-N

物化性质

• 沸点：
  166.8±7.0 °C(Predicted)
• 密度：
  0.864±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  四氢吡咯 、 1-tert-butyl-3-methylcyclopentadiene 以 甲醇 、 乙醚 、 水 、 丙酮 为溶剂， 生成 1,6,6-三甲基-3-叔丁基富烯
  参考文献：
  名称：

  Metallocenes, their preparation, olefin polymerisation catalysts and a process for producing polyolefins

  摘要：

  公开号：

  EP1138687B1
• 作为产物：
  描述：

  3-甲基-2-环戊烯-1-酮 、 叔丁基氯化镁 在 盐酸 、 ammonium chloride 作用下， 以 乙醚 、 水 为溶剂， 生成 1-tert-butyl-3-methylcyclopentadiene
  参考文献：
  名称：

  Metallocenes, their preparation, olefin polymerisation catalysts and a process for producing polyolefins

  摘要：

  公开号：

  EP1138687B1

文献信息

• General Synthetic Route to Substituted Bis(cyclopentadienyl)- and Bis(indenyl)methanes
  作者：Ilya E. Nifant'ev、Pavel V. Ivchenko、Lyudmila G. Kus'mina、Yuri N. Luzikov、Alexander A. Sitnikov、Oleg E. Sizan

  DOI：10.1055/s-1997-1200

  日期：1997.4

  Several substituted bis(cyclopentadienyl)- and bis(indenyl)methanes were synthesized directly from the corresponding cyclopentadienes (indenes) and ketones in KOH/DME two-phase mixture.

  几种取代的双(cyclopentadienyl)-和双(indenyl)甲烷直接从相应的环戊二烯（茚）和酮在KOH/DME双相混合体系中合成。
• Automotive part made of polypropylene resin composition
  申请人：——

  公开号：US20030187121A1

  公开（公告）日：2003-10-02

  An automobile part comprising a polypropylene resin composition, the polypropylene resin composition comprising a propylene homopolymer (A1), an elastomer (B) and an inorganic filler (C), or comprising a propylene block copolymer (A2) and an inorganic filler (C) optionally together with an elastomer (B), in specified proportions. The propylene homopolymer (A1), or the propylene homopolymer segment of the propylene block copolymer (A2) exhibits an MFR (230° C.) of 20 to 300 g/10 min, a ratio of position irregular units derived from 2,1-insertion or 1,3-insertion of propylene monomer relative to all propylene structural units, determined from a 13 C-NMR spectrum, each of 0.2% or less, and an Mw/Mn, determined by GPC, of 1 to 3. The present invention enables providing an automobile part (including an injection molded article) which has an excellent balance of rigidity and impact resistance, on which the possibility of flow marks is low and, even if flow marks occur, they are not conspicuous, and which realizes an excellent emboss transfer on molded article surface to thereby have an excellent appearance. The polypropylene resin composition for use in the present invention has the above formulation, so that the time required for plasticization is short. Consequently, the molding cycle for producing an injection molded article can be shortened to thereby accomplish efficient production of an injection molded automobile part capable of realizing the above effects.

  一种汽车零部件，包括聚丙烯树脂组合物，所述聚丙烯树脂组合物包括丙烯均聚物（A1），弹性体（B）和无机填料（C），或包括丙烯嵌段共聚物（A2）和无机填料（C），可选地与弹性体（B）一起，在指定的比例下混合。丙烯均聚物（A1）或丙烯嵌段共聚物（A2）的丙烯均聚物段具有MFR（230℃）为20至300g/10min，由13C-NMR光谱确定的源自2,1-插入或1,3-插入的丙烯单体的位置不规则单元与所有丙烯结构单元的比率均为0.2％或更少，并且由GPC确定的Mw/Mn为1至3。本发明能够提供一种汽车零部件（包括注塑成型品），其具有优异的刚度和抗冲击性的平衡，在其上流痕的可能性很低，即使出现流痕，它们也不明显，并且在成型品表面实现了优异的压花转移，从而具有优异的外观。本发明所用的聚丙烯树脂组合物具有上述配方，因此，塑化所需的时间很短。因此，用于生产注塑成型品的成型周期可以缩短，从而实现了能够实现上述效果的注塑汽车零部件的高效生产。
• Automobile part of polypropylene resin composition
  申请人：Kawai Koji

  公开号：US20060194914A1

  公开（公告）日：2006-08-31

  An automobile part comprising a polypropylene resin composition, the polypropylene resin composition comprising a propylene homopolymer (A1), an elastomer (B) and an inorganic filler (C) in specified proportions. The polypropylene homopolymer (A1) exhibits an MFR (230° C.) of 20 to 300 g/10 min, a ratio of position irregular units derived from 2,1-insertion or 1,3-insertion of propylene monomer relative to all propylene structural units, determined from a 13 C-NMR spectrum, each of 0.05% or less, and an Mw/Mn, determined by GPC, of 1 to 3.

  一种汽车零件，包括聚丙烯树脂组合物，该聚丙烯树脂组合物包括规定比例的丙烯基同聚物（A1）、弹性体（B）和无机填料（C）。聚丙烯同聚物（A1）在230℃下的熔体流动速率为20至300克/10分钟，从13C-NMR光谱中确定的由2,1-插入或1,3-插入丙烯单体衍生的位置不规则单元与所有丙烯结构单元的比率均小于或等于0.05％，并且由GPC确定的Mw/Mn为1至3。
• Metallocene compound, process for preparing metallocene compund, olefin polymerization catalyst, process for preparing polyolefin, and polyolefin
  申请人：Kawai Koji

  公开号：US20050228155A1

  公开（公告）日：2005-10-13

  The metallocene compound according to the invention and the olefin polymerization catalyst containing the compound are intended to produce a catalyst capable of preparing an isotactic polymer with a high polymerization activity. The metallocene compound contains a substituted cyclopentadienyl group and a (substituted) fluorenyl group and has a structure wherein these groups are bridged by a hydrocarbon group or the like. The process for preparing a metallocene compound according to the invention is intended to selectively prepare a specific metallocene compound so as not to produce an isomer, and in this process an intermediate product is synthesized by a specific method. The process for preparing a polyolefin according to the invention is intended to prepare a polyolefin having excellent impact resistance and transparency, and this process comprises homopolymerizing an α-olefin of 3 to 8 carbon-atoms or copolymerizing an olefin of 3 to 8 carbon atoms and another α-olefin in the presence of an olefin polymerization catalyst containing the above-mentioned metallocene compound.

  本发明的金属茂化合物和含有该化合物的烯烃聚合催化剂旨在生产一个能够制备具有高聚合活性的等规聚物的催化剂。该金属茂化合物含有一个取代环戊二烯基和一个(取代)芴基，并且具有这些基团被碳氢基团或类似物桥接的结构。本发明的制备金属茂化合物的方法旨在选择性地制备特定的金属茂化合物，以避免产生异构体，在该过程中通过特定的方法合成中间产物。本发明的制备聚烯烃的方法旨在制备具有优异的冲击强度和透明度的聚烯烃，该方法包括在上述含有金属茂化合物的烯烃聚合催化剂的存在下，同聚合3到8个碳原子的α-烯烃或共聚合3到8个碳原子的烯烃和另一个α-烯烃。
• Process for Producing Propylene Polymer
  申请人：Funaya Munehito

  公开号：US20080097055A1

  公开（公告）日：2008-04-24

  A high molecular weight propylene polymer exhibiting high stereoregularity (isotactic) and high position selectivity can be effectively produced by polymerizing at least one monomer selected from propylene, α-olefins and polyenes in the presence of a catalyst for olefin polymerization comprising: (A) a bridged metallocene compound represented by the General Formula [I] given in claims (diphenylmethylene(3-tert-butyl-5-ethyl-cyclopentadienyl)(fluorenyl)zirconium dichloride, etc.); and (B) one or more compound(s) selected from (b-1) an organoaluminumoxy compound (b-2) a compound which reacts with the bridged metallocene compound (A) to form an ion pair, and (b-3) an organoaluminum compound.

  高分子量的丙烯聚合物表现出高立构性和高位置选择性，可通过在具有烯烃聚合催化剂的存在下聚合至少选择自丙烯，α-烯烃和多烯之一的单体来有效地生产，所述烯烃聚合催化剂包括：（A）一种由通用式[I]所表示的桥式金属茂化合物（例如，二苯基甲基（3-叔丁基-5-乙基环戊二烯基）（芴基）锆二氯化物）；和（B）一种或多种选择自（b-1）有机铝氧化合物（b-2）与桥式金属茂化合物（A）反应形成离子对的化合物，以及（b-3）有机铝化合物的化合物。