2-甲基-2-[(乙烯基氧基)甲氧基]金刚烷 | 807380-65-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 2-甲基-2-[(乙烯基氧基)甲氧基]金刚烷
• 英文名称: 2-methyl-2-[(vinyloxy)methoxy]adamantane
• 英文别名: 2-[(Ethenyloxy)methoxy]-2-methyltricyclo[3.3.1.1~3,7~]decane；2-(ethenoxymethoxy)-2-methyladamantane
• CAS: 807380-65-0
• 化学式: C₁₄H₂₂O₂
• 分子量: 222.327
• InChiKey: AFWDTYYWDOANCI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-methyl-2-[(2-chloroethoxy)methoxy]adamantane 在 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 以85.0%的产率得到2-甲基-2-[(乙烯基氧基)甲氧基]金刚烷
  参考文献：
  名称：

  Adamantyl vinyl ether compound and production process for the same

  摘要：

  本发明提供了一种具有特定结构的脂肪基乙烯醚化合物，可用作光刻领域功能树脂的单体或其原料，以及医药和农业中间体，以及其生产工艺。本发明涉及一种脂肪基乙烯醚化合物的生产工艺，其特征在于将具有特定结构的脂肪基乙烯醚化合物和具有β位消除基团的醇经过氯烷醚化反应，然后经过醚化反应形成含有脂肪基的醚，最后经过乙烯醚化反应。

  公开号：

  EP1486480A1

文献信息

• Composition and method for preparing linear copolymers of polar and non-polar olefins absent free radical addition polymer
  申请人：Rohm and Haas Company

  公开号：EP1964862A1

  公开（公告）日：2008-09-03

  A polynnerizable composition including a late transition metal complex, a non-polar olefin, a polar olefin, and a free radical scavenger, wherein the polymerizable composition is capable of forming a linear poly[(non-polar olefin)-(polar olefin)] substantially free of free radical addition polymer, is disclosed. A method of copolymerizing a non-polar olefin with a polar olefin, catalyzed by a late transition metal complex in the presence of a free radical scavenger, to produce a linear poly[(non-polar olefin)-(polar olefin)] substantially free of free radical addition polymer is also disclosed.

  本发明公开了一种可聚合组合物，该组合物包括晚过渡金属络合物、非极性烯烃、极性烯烃和自由基清除剂，其中该可聚合组合物能够形成基本上不含自由基加成聚合物的线性聚[（非极性烯烃）-（极性烯烃）]。本发明还公开了一种在游离基清除剂存在下，通过后期过渡金属配合物催化，使非极性烯烃与极性烯烃共聚，从而生成基本上不含游离基加成聚合物的线性聚[（非极性烯烃）-（极性烯烃）]的方法。
• A porous linear polymer composition
  申请人：Rohm and Haas Company

  公开号：EP1964859A1

  公开（公告）日：2008-09-03

  A porous polymer composition including plural linear mixed polarity polymer particles, wherein the particles include a linear poly[(non-polar olefin)-(polar olefin)] and at least one pore, is disclosed, as are those particles further including a catalytic component. A method of forming the plural linear mixed polarity polymer particles is also disclosed. A method of using plural linear mixed polarity polymer particles which include a catalytic component to catalyze polymerization is further disclosed. A porous polymer composition including plural linear non-polar polymer particles and a catalytic component is further disclosed, along with a method of making those linear non-polar polymer particles including the catalytic component and a method of using them to catalyze polymerization.

  本发明公开了一种多孔聚合物组合物，包括多个线性混合极性聚合物颗粒，其中颗粒包括线性聚[（非极性烯烃）-（极性烯烃）]和至少一个孔，这些颗粒还包括催化成分。还公开了一种形成复数线性混合极性聚合物颗粒的方法。还公开了一种使用包含催化成分的复数线性混合极性聚合物颗粒催化聚合的方法。进一步公开了一种包括复数线性非极性聚合物颗粒和催化组分的多孔聚合物组合物，以及制造这些包括催化组分的线性非极性聚合物颗粒的方法和使用它们催化聚合的方法。
• Composition and method for preparing linear copolymers of polar and non-polar olefins free of free radical initiated polymer
  申请人：Rohm and Haas Company

  公开号：EP1964862B1

  公开（公告）日：2010-12-22
• Porous linear polymer composition
  申请人：Acholla Francis V.

  公开号：US20080207789A1

  公开（公告）日：2008-08-28

  A porous polymer composition including plural linear mixed polarity polymer particles, wherein the particles include a linear poly[(non-polar olefin)-(polar olefin)] and at least one pore, is disclosed, as are those particles further including a catalytic component. A method of forming the plural linear mixed polarity polymer particles is also disclosed. A method of using plural linear mixed polarity polymer particles which include a catalytic component to catalyze polymerization is further disclosed. A porous polymer composition including plural linear non-polar polymer particles and a catalytic component is further disclosed, along with a method of making those linear non-polar polymer particles including the catalytic component and a method of using them to catalyze polymerization.
• Composition and method for preparing copolymers of polar and non-polar olefins substantially free of free radical initiated polymer
  申请人：Goodall Brian Leslie

  公开号：US20080207856A1

  公开（公告）日：2008-08-28

  A polymerizable composition including a late transition metal complex, a non-polar olefin, a polar olefin, and a free radical scavenger, wherein the polymerizable composition is capable of forming a linear poly[(non-polar olefin)-(polar olefin)] substantially free of free radical addition polymer, is disclosed. A method of copolymerizing a non-polar olefin with a polar olefin, catalyzed by a late transition metal complex in the presence of a free radical scavenger, to produce a linear poly[(non-polar olefin)-(polar olefin)] substantially free of free radical addition polymer is also disclosed.