5-(Pent-4-EN-1-YL)oxolan-2-one | 61167-11-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酯类
• 英文名称: 5-(Pent-4-EN-1-YL)oxolan-2-one
• 英文别名: 5-pent-4-enyloxolan-2-one
• CAS: 61167-11-1
• 化学式: C₉H₁₄O₂
• 分子量: 154.209
• InChiKey: ZBYMVCKQRDYCME-UHFFFAOYSA-N

物化性质

• 沸点：
  259.0±9.0 °C(Predicted)
• 密度：
  0.973±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-hydroxy-octanimidoyl chloride 、 5-(Pent-4-EN-1-YL)oxolan-2-one 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 生成 5-[3-(3-Heptyl-4,5-dihydro-1,2-oxazol-5-yl)propyl]oxolan-2-one
  参考文献：
  名称：

  Modification of the side chain of micromolide, an anti-tuberculosis natural product

  摘要：

  This paper describes a series of modi. cations of the side chain of micromolide, an anti-tuberculosis natural product. Most of the synthesized compounds showed significantly decreased activities, which suggests that the long aliphatic side chain of micromolide and its double bond are essential to its activity. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.bmcl.2008.08.027
• 作为产物：
  描述：

  4-[(三甲基硅基)乙炔基]吗啉 、 2-(pent-4-en-1-yl)oxirane 在 三氟化硼乙醚 、 potassium hydrogen bifluoride 作用下， 以 二氯甲烷 、 水 、 乙腈 为溶剂， 反应 0.57h， 生成 5-(Pent-4-EN-1-YL)oxolan-2-one
  参考文献：
  名称：

  Modification of the side chain of micromolide, an anti-tuberculosis natural product

  摘要：

  This paper describes a series of modi. cations of the side chain of micromolide, an anti-tuberculosis natural product. Most of the synthesized compounds showed significantly decreased activities, which suggests that the long aliphatic side chain of micromolide and its double bond are essential to its activity. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.bmcl.2008.08.027

文献信息

• Mechanisms for Manganese(III) Oxidations with Alkenes
  作者：William E. Fristad、John R. Peterson、Andreas B. Ernst、Gordon B. Urbi

  DOI：10.1016/s0040-4020(01)87310-5

  日期：1986.1

  metal complexed organic radicals, and the importance of an oxo-centered manganese(III) triangle are discussed as they relate to the lactone annulation reaction. Single electron transfer oxidation of alkenes is described as a route toward 1,2-diacetates of alkenes within the 8.1-7.5 eV I.P. range. Three less common modes of Mn(III) reaction are discussed and compared with the two primary processes of

  在乙酸锰（III）与羧酸和烯烃的反应中，已经鉴定出三个不同的过程，它们涉及烯烃和两个独立于烯烃的过程。通过产品研究，重排，稀释实验和文献动力学数据的组合，可以提出一个统一的机制图来描述这些过程。具体地，讨论了羧酸组分的α-H酸的作用，缺电子的自由基加成，金属络合的有机自由基以及以氧代为中心的锰（III）三角形的重要性，因为它们与内酯环化反应有关。烯烃的单电子转移氧化被描述为通往8.1-7.5 eV IP范围内的烯烃1,2-二乙酸酯的途径。
• Polyhydroxyalkanoic Acid Having Vinyl, Ester, Carboxyl or Sulfonic Acid Group and Producing Method Therefor
  申请人：Kenmoku Takashi

  公开号：US20080064828A1

  公开（公告）日：2008-03-13

  The invention is to provide a novel polyhydroxyalkanoate having a reactive function group within the molecule and a producing method therefor In a polyhydroxyalkanoate containing a unit having a vinyl group in a side chain, such vinyl group is utilized for deriving a polyhydroxyalkanoate comprising a carboxyl group or a unit having an amide group and a sulfonic acid group.

  本发明旨在提供一种新型聚羟基烷酸酯，其分子内具有反应性功能团，并提供其制备方法。在含有侧链中具有乙烯基团的聚羟基烷酸酯中，利用该乙烯基团来获得含有羧基或含有酰胺基和磺酸基的聚羟基烷酸酯。
• SLOW-RELEASE FORMULATION CONTAINING GEL COMPOSITION FOR USE ON PESTS
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP2805615A1

  公开（公告）日：2014-11-26

  Provided is a sustained release preparation comprising an insect pest-targeting gel composition, the preparation being free from leakage or reaction of a volatile substance and being capable of releasing the volatile substance at a constant rate. More specifically, provided is a sustained release preparation comprising a polymer tube and an insect pest-targeting gel composition in the polymer tube, the composition comprising one or more volatile substances and an oil gelling agent, wherein the volatile substances are comprised in an amount of from 70.0 to 99.0% by weight by the insect pest-targeting composition and are released outside of the polymer tube through the polymer tube.

  本发明提供了一种包含害虫靶向凝胶组合物的缓释制剂，该制剂中的挥发性物质不会泄漏或发生反应，并且能够以恒定的速率释放挥发性物质。更具体地说，本发明提供了一种持续释放制剂，包括聚合物管和聚合物管中的害虫靶向凝胶组合物，该组合物包括一种或多种挥发性物质和油胶凝剂，其中挥发性物质的含量为害虫靶向组合物重量的 70.0% 至 99.0%，并通过聚合物管释放到聚合物管外。
• Insect pest-targeting gel composition and sustained release preparation comprising that
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10244750B2

  公开（公告）日：2019-04-02

  Provided are an insect pest-targeting gel composition causing neither leakage nor reaction of a volatile substance and capable of releasing the volatile substance at a constant rate; and a sustained release preparation including the insect pest-targeting gel composition. More specifically, provided is an insect pest-targeting gel composition including one or more volatile substances and an oil gelling agent, wherein the volatile substance is included in an amount of from 70.0 to 99.0% by weight by the insect pest-targeting gel composition.

  本发明提供了一种害虫靶向凝胶组合物，该组合物不会导致挥发性物质泄漏或反应，并能以恒定速率释放挥发性物质；还提供了一种包含该害虫靶向凝胶组合物的缓释制剂。更具体地说，提供了一种包含一种或多种挥发性物质和油胶凝剂的害虫靶向凝胶组合物，其中挥发性物质的含量为害虫靶向凝胶组合物重量的 70.0% 至 99.0%。
• Manganese(III)-mediated .gamma.-lactone annulation
  作者：William E. Fristad、John R. Peterson

  DOI：10.1021/jo00201a003

  日期：1985.1