p-menth-8-en-7-oic acid methyl ester | 135727-83-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: p-menth-8-en-7-oic acid methyl ester
• 英文别名: p-Menth-8-en-7-saeure-methylester；methyl 4-prop-1-en-2-ylcyclohexane-1-carboxylate
• CAS: 135727-83-2
• 化学式: C₁₁H₁₈O₂
• 分子量: 182.263
• InChiKey: BPHNIGJZJBBHCU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  碘甲烷 、 alkaline earth salt of/the/ methylsulfuric acid 生成 p-menth-8-en-7-oic acid methyl ester
  参考文献：
  名称：

  Semmler; Zaar, Chemische Berichte, 1911, vol. 44, p. 54,461

  摘要：

  DOI：

文献信息

• TMSCN/DBU-Mediated Facile Redox Transformation of α,β-Unsaturated Aldehydes to Carboxylic Acid Derivatives
  作者：Hiromi Kaise、Jun Shimokawa、Tohru Fukuyama

  DOI：10.1021/ol403415z

  日期：2014.2.7

  Redox transformation of an α,β-unsaturated aldehyde to a carboxylic acid derivative by means of a combination of TMSCN and DBU was investigated. In addition to the wide use of the carboxylic acid derivatives provided by this reaction, temperature-dependent control of the kinetic or thermodynamic protonation pattern was found to selectively switch the stereochemistry of the acyl group in the product

  研究了通过TMSCN和DBU的组合将α，β-不饱和醛氧化还原为羧酸衍生物。除了该反应提供的羧酸衍生物的广泛使用之外，发现动力学或热力学质子化模式的温度依赖性控制可选择性地切换产物中酰基的立体化学。
• METHODS AND COMPOSITIONS FOR STIMULATING THE PRODUCTION OF HYDROCARBONS FROM SUBTERRANEAN FORMATIONS
  申请人：Cesi Chemical Inc.

  公开号：EP3008283A1

  公开（公告）日：2016-04-20
• [EN] COMPOSITIONS COMPRISING AROMATIC ESTER SOLVENTS FOR USE IN OIL AND/OR GAS WELLS AND RELATED METHODS<br/>[FR] COMPOSITIONS COMPRENANT DES SOLVANTS DE TYPE ESTER AROMATIQUE DESTINÉES À ÊTRE UTILISÉES DANS DES PUITS DE PÉTROLE ET/OU DE GAZ ET PROCÉDÉS ASSOCIÉS
  申请人：FLOTEK CHEMISTRY LLC

  公开号：WO2019036665A1

  公开（公告）日：2019-02-21

  Compositions comprising aromatic ester solvents for use in various aspects of a life cycle of an oil and/or gas well, and related methods, are provided. In some embodiments, the composition includes an emulsion or microemulsion wherein the emulsion or microemulsion comprises an aqueous phase, a surfactant, and a non-aqueous phase. In some embodiments, the non-aqueous phase comprises a solvent blend including a first type of solvent and a second type of solvent, e.g., having a respective weight ratio of about 3:2 to 1:4. In some embodiments, the first type of solvent is a terpene and/or the second type of solvent is an aromatic ester solvent. In some embodiments, compositions are used in methods for treating an oil and/or gas well having a wellbore. In some embodiments, the composition is delivered into the wellbore, reducing residues comprising kerogens, asphaltenes, paraffins, organic scale, or combinations thereof on or near the wellbore.
• Semmler; Zaar, Chemische Berichte, 1911, vol. 44, p. 54,461
  作者：Semmler、Zaar

  DOI：——

  日期：——