(Z)-1-(tributylstannyl)-4(triethylgermyl)-2-methyl-3-buten-2-ol | 342901-17-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (Z)-1-(tributylstannyl)-4(triethylgermyl)-2-methyl-3-buten-2-ol
• CAS: 342901-17-1
• 化学式: C₂₃H₅₀GeOSn
• 分子量: 533.949
• InChiKey: ORDFQIKEBYBVQS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.65
• 重原子数：
  26
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  (triethylgermyl)tributylstannane 、 2-甲基-3-丁炔-2-醇 在 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 三羟甲基丙烷亚磷酸酯 作用下， 以 四氢呋喃 为溶剂， 以85%的产率得到(Z)-1-(tributylstannyl)-4(triethylgermyl)-2-methyl-3-buten-2-ol
  参考文献：
  名称：

  Synthesis of (Z)-1-aryl-2-(germyl)-1-(stannyl)ethenes and the related ethenes, precursors to stereodefined germylethenes, via Pd(dba)2–P(OCH2)3CEt-catalyzed germastannation of acetylenes in THF

  摘要：

  (Z)-1-Aryl-2-(germyl)-1-(stannyl)ethenes are synthesized in high yields by the addition of tributyl(triethylgermyl)stannane to arylacetylenes catalyzed by a specific combination catalyst, Pd(dba)(2) and 4-ethyl-1-phospha-2,6,7-trioxabicyclo[2.2.2]octane, in tetrahydrofuran. Ethynylthiophene and 2-methyl-3-butyn-2-ol are also subject to the germastannation to afford the respective adducts in high yields. In addition, the J(Sn-H) and C-13-NMR data for their adducts are presented. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00652-0

文献信息

• Synthesis of (Z)-1-aryl-2-(germyl)-1-(stannyl)ethenes and the related ethenes, precursors to stereodefined germylethenes, via Pd(dba)2–P(OCH2)3CEt-catalyzed germastannation of acetylenes in THF
  作者：Yoshiya Senda、Yoh-ichi Oguchi、Michihiro Terayama、Taijyu Asai、Taichi Nakano、Toshihiko Migita

  DOI：10.1016/s0022-328x(01)00652-0

  日期：2001.3

  (Z)-1-Aryl-2-(germyl)-1-(stannyl)ethenes are synthesized in high yields by the addition of tributyl(triethylgermyl)stannane to arylacetylenes catalyzed by a specific combination catalyst, Pd(dba)(2) and 4-ethyl-1-phospha-2,6,7-trioxabicyclo[2.2.2]octane, in tetrahydrofuran. Ethynylthiophene and 2-methyl-3-butyn-2-ol are also subject to the germastannation to afford the respective adducts in high yields. In addition, the J(Sn-H) and C-13-NMR data for their adducts are presented. (C) 2001 Elsevier Science B.V. All rights reserved.