2-羟基-1-苯基庚烷-1-酮 | 100568-28-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 2-羟基-1-苯基庚烷-1-酮
• 英文名称: 2-Hydroxy-1-phenylheptan-1-one
• CAS: 100568-28-3
• 化学式: C₁₃H₁₈O₂
• 分子量: 206.285
• InChiKey: BRTHMFXKGHIZAM-UHFFFAOYSA-N

物化性质

• 沸点：
  316.4±15.0 °C(Predicted)
• 密度：
  1.024±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-羟基-1-苯基庚烷-1-酮 、 O-(triisopropylsilyl)hydroxylamine 以 甲苯 为溶剂， 以72%的产率得到
  参考文献：
  名称：

  对映选择性Cu-H-催化的Si-O偶联的α-羟基取代的肟醚的动力学拆分

  摘要：

  据报道，通过Cu-H催化的α-羟基与肟醚和简单的氢硅烷的脱氢Si-O偶联，可以控制催化剂控制的对映选择性醇的甲硅烷基化反应。在此动力学拆分达到选择性的因素通常是高（š ≈50），和这些反应从而提供对映体富集的高度α羟基-取代的肟醚的可靠访问。还证明了这些化合物的合成有用性。

  DOI：

  10.1002/anie.201802947
• 作为产物：
  描述：

  苯甲醛 、 正己醛 在 2-pentafluorophenyl-6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-2-ium tetrafluoroborate 、 caesium carbonate 作用下， 以 间二甲苯 为溶剂， 反应 24.0h， 以91%的产率得到1-羟基-1-苯基庚烷-2-酮
  参考文献：
  名称：

  使用坚固的N杂环卡宾催化剂，多种芳香族和脂肪族醛之间的化学选择性和重复性分子间交叉酰基酰基缩合反应†

  摘要：

  我们发现，通过调节芳族醛/脂族醛比率来控制交叉的酰胆素产物的化学选择性。此外，由于NHC催化剂的坚固性，我们观察到了溶液中均相NHC催化剂的持久催化活性。

  DOI：

  10.1039/c3ob42486c

文献信息

• Development of a Bio-Inspired Acyl-Anion Equivalent Macrocyclization and Synthesis of a <i>trans-</i>Resorcylide Precursor
  作者：Steven M. Mennen、Scott J. Miller

  DOI：10.1021/jo070676d

  日期：2007.7.1

  N-pentafluorophenyl triazolium variant led to cyclization at room temperature within a short 90-min reaction time. These findings were applied to a range of substrates, including the synthesis of a key intermediate in a rapid synthesis of trans-resorcylide.

  关于α，ω-二醛的大环化的研究表明，在反应的最终效率方面强烈依赖于环的大小。观察到强烈的催化剂依赖性，因为噻唑鎓盐导致没有可检测的产物形成，而缺电子的三唑鎓盐用作环化的预催化剂。出人意料的是，N-五氟苯基三唑鎓变体导致在室温下短短90分钟的反应时间内环化。这些发现被应用于一系列底物，包括快速合成反式间苯二酚的关键中间体的合成。
• Radiation-curing resin composition
  申请人：DAINIPPON INK AND CHEMICALS, INC.

  公开号：EP0529361A1

  公开（公告）日：1993-03-03

  A radiation-curing resin composition comprising (A) a resin having a carboxylic acid group and an unsaturated double bond, and (B) a compound containing a cyclocarbonate group. The composition is excellent in stability and curing properties and provides a cured film excellent in water resistance, solvent resistance, chemical resistance, and heat resistance.

  一种辐射固化树脂组合物，由 (A) 具有羧酸基团和不饱和双键的树脂和 (B) 含有环碳酸酯基团的化合物组成。该组合物具有优异的稳定性和固化性能，并能提供具有优异的耐水性、耐溶剂性、耐化学性和耐热性的固化薄膜。
• Radiation curable polymers and method of producing the same
  申请人：DAINIPPON INK AND CHEMICALS, INC.

  公开号：EP0735426A1

  公开（公告）日：1996-10-02

  The present invention provides a radiation curable resin composition and method of production therefor; the present composition has wide applications as an ink, coating or the like, is dilutable in water or an organic solvent, and forms a coating which has excellent hardening characteristics and adherence to a substrate, as well as superior resistance to heat, chemicals and boiling, this resin composition may be redissolved with water or an organic solvent prior to hardening; which have a number average weight of 500 to 50,000, characterized in that the aprotic ammonium salt represented by general formula 1 is contained in the resin in the amount of 0.1 to 4.0 mol/kg. (In the formula, X is an organic group which is bound to the main chain and includes a hydrocarbon of 0 to 3 carbon atoms, an ester and an amide; R1 and R2, which may be the same or different, represent a hydrocarbon of 1 to 8 carbons which may be substituted with a hydroxyl group, ester group, alkoxy group or halogen atom, wherein R1 and R2 may bond together, with bonding occurring between the nitrogen atoms of R1 and R2 to form a heterocyclic ring; R3 indicates a hydrogen atom or a hydrocarbon of 1 to 18 carbon atoms that has one or more polymerizable unsaturated double bonds and may be substituted with a hydroxyl group, ester group, alkoxy group, or halogen atom; and R4, R5 and R6, which may be the same or different, represent a hydrogen atom or a hydrocarbon of 1 to 18 carbons which may be substituted with a hydroxyl group, ester group, alkoxy group, or halogen atom, wherein R5 and R6 may bond together to form a heterocyclic ring.)

  本发明提供了一种可辐射固化的树脂组合物及其生产方法；本发明组合物可广泛应用于油墨、涂料或类似用途，可在水中或有机溶剂中稀释，形成的涂层具有优异的硬化特性和对基材的附着力，以及优异的耐热性、耐化学性和耐沸腾性，这种树脂组合物可在硬化前用水或有机溶剂重新溶解；(2)一种树脂组合物，其平均重量为 500 至 50,000，其特征在于通式 1 所代表的烷基铵盐在树脂中的含量为 0.1 至 4.0 摩尔/千克。1至4.0摩尔/千克。 (式中，X 是与主链结合的有机基团，包括 0 至 3 个碳原子的烃、酯和酰胺；R1 和 R2 可以相同或不同，代表 1 至 8 个碳原子的烃，可以被羟基、酯基、烷氧基或卤原子取代，其中 R1 和 R2 可以键合，键合发生在 R1 和 R2 的氮原子之间，形成杂环；R3 表示氢原子或 1 至 18 个碳原子的烃，该烃具有一个或多个可聚合的不饱和双键，可被羟基、酯基、烷氧基或卤素原子取代；以及 R4、R5 和 R6（可相同或不同）表示氢原子或 1 至 18 个碳原子的烃，该烃可被羟基、酯基、烷氧基或卤素原子取代，其中 R5 和 R6 可键合在一起形成杂环。)
• DISPLAY APPARATUS AND CELLULAR PHONE,COMPUTER AND TELEVISION INCLUDING THE SAME
  申请人：Sun, Runwen

  公开号：EP2133736A1

  公开（公告）日：2009-12-16

  A display apparatus (100') includes a substrate (115a) and a light switch (210). A light source (310') is provided at the side of the substrate (115a) and emits light of which wavelength is in the range of ultraviolet or cyan. A polarizing sheet (116), as well as a photoluminescence film (110'), is provided in front of the light source (310'). Under the excitation of the light source (310'), the photoluminescence film (110') can emit red light, green light, blue light and/or intermediate color light among red, green and blue.

  显示设备 (100') 包括一个基板 (115a) 和一个光开关 (210)。光源（310'）设置在基板（115a）的一侧，并发出波长在紫外线或青光范围内的光。在光源（310'）前方设有偏振片（116）和光致发光薄膜（110'）。在光源（310'）的激发下，光致发光薄膜（110'）可以发出红光、绿光、蓝光和/或红、绿、蓝之间的中间色光。
• Melt-flow controlling method for elastomer by uv irradiation
  申请人：Kim Tae-Sung

  公开号：US20050016672A1

  公开（公告）日：2005-01-27

  A melt-flow controlling method for elastomer by uv irradiation for use in semiconductor packages by ultraviolet irradiation, in which a coated polymer composition is crosslinked by ultraviolet irradiation after a coating process of the polymer composition in producing the elastic adhesives. In producing the elastic adhesives for use as the thermal stress relief layer in semiconductor packages, the inventive method comprises irradiating the polymer composition with ultraviolet light of a 100-500 nm wavelength in order to control the flowability and crosslinking degree of the coated polymer composition. Thus, according to the present invention, a heating furnace is not used such that energy consumption can be reduced. Also, curing can be achieved in a short time so as to increase productivity, and the crosslinking degree is easily controlled by changing the ultraviolet dose as compared to the thermal crossliking process. Furthermore, an installation area of ultraviolet irradiation equipment is smaller than the heating furnace, and little or no epoxy reactive groups participate in the crosslinking reaction upon photo-polymerization so that the resulting film product has an excellent storage stability and thus a long life span.

  一种通过紫外线辐照控制用于半导体封装的弹性体熔体流动的方法，其中在生产弹性粘合剂时，在聚合物组合物的涂覆工序之后，通过紫外线辐照使涂覆的聚合物组合物交联。在生产用作半导体封装热应力消除层的弹性粘合剂时，本发明的方法包括用波长为 100-500 纳米的紫外线照射聚合物组合物，以控制涂覆聚合物组合物的流动性和交联度。因此，根据本发明，无需使用加热炉，从而可以降低能耗。此外，固化可在短时间内完成，从而提高生产率，而且与热交联工艺相比，通过改变紫外线剂量可轻松控制交联度。此外，紫外线辐照设备的安装面积比加热炉小，而且在光聚合时，很少或根本没有环氧反应基团参与交联反应，因此生成的薄膜产品具有极佳的储存稳定性，使用寿命长。