stelliferin M | 1332832-02-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: stelliferin M
• 英文别名: [(3Z,3aS,5aR,7S,9aR,9bS)-3-[(E)-4-[(1R,2S,3S)-2,3-dihydroxy-2-methyl-5-propan-2-ylidenecyclopentyl]but-3-en-2-ylidene]-3a,6,6,9a-tetramethyl-2-oxo-1,4,5,5a,7,8,9,9b-octahydrocyclopenta[a]naphthalen-7-yl] acetate
• CAS: 1332832-02-6
• 化学式: C₃₂H₄₈O₅
• 分子量: 512.73
• InChiKey: AVSAIZGJLCXGBZ-DVCGLEBZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  37
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  83.8
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  stelliferin M 在 甲醇 、 potassium carbonate 作用下， 反应 20.0h， 生成
  参考文献：
  名称：

  Stelliferins J–N, isomalabaricane-type triterpenoids from Okinawan marine sponge Rhabdastrella cf. globostellata

  摘要：

  Five new isomalabaricane-type triterpenoids, stelliferins J-N (1-5), were isolated from Okinawan marine sponge Rhabdastrella cf. globostellata. The structures of 1-5 were elucidated from the spectroscopic data and chemical means including application of a modified Mosher's method and an exciton chirality method. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2011.04.095

文献信息

• Stelliferins J–N, isomalabaricane-type triterpenoids from Okinawan marine sponge Rhabdastrella cf. globostellata
  作者：Naonobu Tanaka、Rei Momose、Azusa Shibazaki、Tohru Gonoi、Jane Fromont、Jun’ichi Kobayashi

  DOI：10.1016/j.tet.2011.04.095

  日期：2011.9

  Five new isomalabaricane-type triterpenoids, stelliferins J-N (1-5), were isolated from Okinawan marine sponge Rhabdastrella cf. globostellata. The structures of 1-5 were elucidated from the spectroscopic data and chemical means including application of a modified Mosher's method and an exciton chirality method. (C) 2011 Elsevier Ltd. All rights reserved.