(3E,5E,7E,9E,11E)-HCC(CH=CH)5-CCH | 947507-50-8

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: (3E,5E,7E,9E,11E)-HCC(CH=CH)5-CCH
• 英文别名: (3E,5E,7E,9E,11E)-tetradeca-3,5,7,9,11-pentaen-1,13-diyne
• CAS: 947507-50-8
• 化学式: C₁₄H₁₂
• 分子量: 180.249
• InChiKey: BLLSOHLINSZBIT-IPPUEFGVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (3E,5E,7E,9E,11E)-HCC(CH=CH)5-CCH 、 [RuHCl(CO)(PPh₃)₃] 以 二氯甲烷 为溶剂， 生成 [RuCl(PPh3)2]2(μ-(CH=CH)7]
  参考文献：
  名称：

  Synthesis and characterization of bimetallic ruthenium complexes connected through linear (CH)14 chain

  摘要：

  Treatment of RuHCl(CO)(PPh3)(3) with (3E,5E,7E,9E,11E)-HC C-(CH=CH)(5)-C CH produces [RuCl(CO)(PPh3)(2)](2)[mu-(CH=CH)(7)]. The later complex reacts with PMe3 to give [RuCl(CO)(PMe3)(3)](2)[mu-(CH=CH)(7)], the structure of which has been confirmed by X-ray diffraction. The through-space distance from one Ru to the other is 19.88 angstrom. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.04.040
• 作为产物：
  描述：

  (E)-5-(trimethylsilyl)pent-2-en-4-ynal 、 (E)-but-2-ene-1,4-diylbis(tributylphosphonium) dibromide 在 sodium ethanolate 作用下， 以 乙醇 为溶剂， 反应 48.0h， 以67%的产率得到(3E,5E,7E,9E,11E)-HCC(CH=CH)5-CCH
  参考文献：
  名称：

  Synthesis and characterization of bimetallic ruthenium complexes connected through linear (CH)14 chain

  摘要：

  Treatment of RuHCl(CO)(PPh3)(3) with (3E,5E,7E,9E,11E)-HC C-(CH=CH)(5)-C CH produces [RuCl(CO)(PPh3)(2)](2)[mu-(CH=CH)(7)]. The later complex reacts with PMe3 to give [RuCl(CO)(PMe3)(3)](2)[mu-(CH=CH)(7)], the structure of which has been confirmed by X-ray diffraction. The through-space distance from one Ru to the other is 19.88 angstrom. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.04.040

文献信息

• Synthesis and characterization of bimetallic ruthenium complexes connected through linear (CH)14 chain
  作者：Ping Yuan、Xiang-hua Wu、Guang-ao Yu、Dan Du、Sheng Hua Liu

  DOI：10.1016/j.jorganchem.2007.04.040

  日期：2007.7

  Treatment of RuHCl(CO)(PPh3)(3) with (3E,5E,7E,9E,11E)-HC C-(CH=CH)(5)-C CH produces [RuCl(CO)(PPh3)(2)](2)[mu-(CH=CH)(7)]. The later complex reacts with PMe3 to give [RuCl(CO)(PMe3)(3)](2)[mu-(CH=CH)(7)], the structure of which has been confirmed by X-ray diffraction. The through-space distance from one Ru to the other is 19.88 angstrom. (c) 2007 Elsevier B.V. All rights reserved.