acetaldehyde dicyclohexyl acetal | 5314-42-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: acetaldehyde dicyclohexyl acetal
• 英文别名: 1-Cyclohexyloxyethoxycyclohexane
• CAS: 5314-42-1
• 化学式: C₁₄H₂₆O₂
• 分子量: 226.359
• InChiKey: GFKGCRXDRKJNES-UHFFFAOYSA-N

物化性质

• 沸点：
  136 °C(Press: 11 Torr)
• 密度：
  0.9535 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  盐酸 、 acetaldehyde dicyclohexyl acetal 、 水 生成 乙醛 、 环己醇
  参考文献：
  名称：

  Minne; Adkins, Journal of the American Chemical Society, 1933, vol. 55, p. 301

  摘要：

  DOI：
• 作为产物：
  描述：

  (1-氯-乙基)-环己基醚 在 氨 作用下， 生成 acetaldehyde dicyclohexyl acetal
  参考文献：
  名称：

  Bogdanowa et al., Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1957, p. 345,349; engl. Ausg. S. 357, 360

  摘要：

  DOI：

文献信息

• PROCESS FOR PRODUCTION OF HIGH-PURITY VINYL ETHER
  申请人：TENJIMBAYASHI Ryuichi

  公开号：US20100249465A1

  公开（公告）日：2010-09-30

  A process for producing a high-purity vinyl ether, which comprises: a step of subjecting an alcohol represented by the general formula (1) R—O—H  (1) to a vinyl ether formation reaction in the presence of a catalyst to synthesize a vinyl ether represented by the general formula (2), R—O—CH═CH 2 (2) a step of removing the catalyst from the reaction mixture obtained in the above step to obtain a crude vinyl ether containing the vinyl ether and the unreacted raw material alcohol, a step of reacting the unreacted raw material alcohol in the crude vinyl ether, with the vinyl ether in the presence of an acid catalyst, to convert the alcohol into an acetal represented by the general formula (3), and a step of subjecting a crude vinyl ether containing the acetal (III) to distillation to obtain a high-purity vinyl ether.

  生产高纯度乙烯醚的方法，包括：在催化剂存在下，将通式（1）R—O—H代表的醇进行乙烯醚形成反应，合成通式（2）R—O—CH═CH2代表的乙烯醚的步骤；从上述步骤得到的反应混合物中去除催化剂，得到含有乙烯醚和未反应原料醇的粗乙烯醚的步骤；在酸催化剂存在下，将粗乙烯醚中的未反应原料醇与乙烯醚反应，将醇转化为通式（3）代表的缩醛的步骤；将含有缩醛（III）的粗乙烯醚经过蒸馏，得到高纯度乙烯醚的步骤。
• A Facile One-Pot Synthesis of Symmetrical and Unsymmetrical Acetaldehyde Acetals from Primary Alcohols
  作者：Rodney Kiplin Guy、Richard Anthony DiPietro

  DOI：10.1080/00397919208019270

  日期：1992.3

  alcohol 1 with ethyl vinyl ether in the presence of mercury (11) acetate followed by treatment with the same or a different alcohol in the presence of p-toluenesulfonic acid affords the symmetrical and unsymmetrical acetaldehyde acetals 3 in good overall yield. The method is easily scaled up and represents a significant improvement over currently available procedures.

  摘要 在乙酸汞 (11) 存在下用乙基乙烯基醚处理伯醇 1，然后在对甲苯磺酸存在下用相同或不同的醇处理，初步形成乙烯基醚 2，得到对称和不对称乙醛缩醛 3 的总产率良好。该方法很容易扩大规模，并代表了对当前可用程序的显着改进。
• Processes for preparing calanolide a and intermediates thereof
  申请人：——

  公开号：US20040106808A1

  公开（公告）日：2004-06-03

  The present invention provides a production method of Calanolide A according to the following method 1 wherein each symbol is as defined in the specification, as a more convenient and industrially practical method for the synthesis of Calanolide A from an easily available starting material.

  本发明提供了一种Calanolide A的生产方法，根据以下方法1，其中每个符号如规范中定义，作为从易得到的起始材料合成Calanolide A的更方便和工业实用的方法。
• Mixtures of pyramidal columnar liquid crystals and procedure for their preparation
  申请人：ECP ENICHEM POLIMERI S.r.l.

  公开号：EP0431934A2

  公开（公告）日：1991-06-12

  Mixtures of pyramidal columnar liquid crystals made up of dodeca-substituted derivatives of macrocyclic tetramers wherein each of the substituents is either linear or branched alkanoyl chain of different lengths and randomly distributed. These mixtures show stable mesophases of the columnar type having a wide temperature range which also includes room temperature.

  由十二碳原子取代的大环四聚体衍生物组成的金字塔柱状液晶混合物，其中每个取代基都是不同长度和随机分布的线性或支链烷酰基链。这些混合物显示出稳定的柱状介相，其温度范围很广，包括室温。
• PROCESSES FOR PREPARING CALANOLIDE A AND INTERMEDIATES THEREOF
  申请人：Kuraray Co., Ltd.

  公开号：EP1352907A1

  公开（公告）日：2003-10-15

  The present invention provides a production method of Calanolide A according to the following method Scheme 1 wherein each symbol is as defined in the specification, as a more convenient and industrially practical method for the synthesis of Calanolide A from an easily available starting material.

  本发明根据以下方法提供了一种 Calanolide A 的生产方法 方案 1 其中各符号如说明书中所定义，是一种从容易获得的起始原料合成Calanolide A的更方便和工业实用的方法。