5,10-dimethyl-1,14-diphenyl-6,9-diazatetradeca-4,10-diene-1,3,12,14-tetraone | 58894-69-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5,10-dimethyl-1,14-diphenyl-6,9-diazatetradeca-4,10-diene-1,3,12,14-tetraone
• 英文别名: N,N'-ethylenebis(benzoylacetylacetone)-2,2'-imine；5-[2-[(4,6-Dioxo-6-phenylhexan-2-ylidene)amino]ethylimino]-1-phenylhexane-1,3-dione
• CAS: 58894-69-2
• 化学式: C₂₆H₂₈N₂O₄
• 分子量: 432.519
• InChiKey: IRNOKCYLSBJICZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  32
• 可旋转键数：
  13
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  93
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  5,10-dimethyl-1,14-diphenyl-6,9-diazatetradeca-4,10-diene-1,3,12,14-tetraone 以 甲醇 、 水 、 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Lintvedt; Ahmad, Inorganic Chemistry, 1982, vol. 21, # 6, p. 2356 - 2359

  摘要：

  DOI：

文献信息

• Compartmental ligands. Part 2. Mononuclear transition-metal complexes of acyclic Schiff bases derived from 1,3,5-triketones
  作者：David E. Fenton、Stephen E. Gayda

  DOI：10.1039/dt9770002101

  日期：——

  A series of acyclic Schiff bases (1) derived from 1,3,5-triketones and α,ω-alkanediamines has been prepared, and their mononuclear complexes with CuII, NiII, UO2, and VO are described. Phenyl-substituted alicyclic bases are prepared by the reaction of 1-p-X-phenylhexane-1,3,5-trione (X = H, Br, Me, or OMe)(2 mol) and ethane-1,2-diamine (en)(1 mol) in ethanol; the condensation of 7,7-dimethyloctane-2

  制备了一系列由1,3,5-三酮和α，ω-烷二胺衍生的无环席夫碱（1），并描述了它们与Cu II，Ni II，UO 2和VO的单核配合物。苯基取代的脂环族碱是通过1- p反应制备的-X-苯基己烷-1,3,5-三酮（X = H，Br，Me或OMe）（2摩尔）和乙烷-1,2-二胺（en）（1摩尔）的乙醇溶液; 7,7-二甲基辛烷-2,4,6-三酮与en的缩合反应类似地产生2,2,7,12,17,17-六甲基-8,11-二氮杂十八烷基-6,12-二烯-3,5， 14,16-四酮（1 I）。6，6-11-Dimethyl-7,10-diazahexadeca-5,11-diene-2,4,13,15-tetraone，（1a）是通过酸水解大环Schiff碱5,9,14,18制备的（1 a） -四甲基-1,4,10,13-四氮杂环-十八烷基-5,8,14,17-四烯-7,16-二酮（2a）。用乙酸金属
• Compartmental ligands. Part 3. Homo- and hetero-binuclear transition-metal complexes of acyclic Schiff bases derived from 1,3,5-triketones
  作者：David E. Fenton、Stephen E. Gayda

  DOI：10.1039/dt9770002109

  日期：——

  Acyclic Schiff bases derived from 1,3,5-triketones and α,ω-alkanediamines have two ligand compartments for metal co-ordination, one based on N2O2, and the other on O2O2 donor sets. Homo- and hetero-binuclear metal complexes of such ligands have been prepared and the nature of the site occupancy investigated. The mononuclear complexes [6,11-dimethyl-7,10-diazahexadeca-5, 11-diene-2,4,13,15-tetraona

  衍生自1,3,5-三酮和α，ω-烷二胺的无环席夫碱具有两个配位区用于金属配位，一个基于N 2 O 2，另一个基于O 2 O 2供体组。已经制备了这种配体的同核和异核双金属配合物，并研究了位点占据的性质。单核络合物[6,11-二甲基-7,10-二氮杂十六烷-5，11-二烯-2,4,13,15-四onato（2 –）- N 7 N 10 O 4 O 13 ]铜（II）（ 5a； M = Cu）和5,10-二甲基-1,14-二苯基-6,9-二氮杂铜盐-4,10-二烯-1,3,12,14-四onato（2 –）- N 6 N 9 O3 O 12 ]铜（ II）（5m； M = Cu）已用各种金属乙酸盐（ II）处理，得到Cu 2，Ni 2，CuUO 2，CuVO，CuZn，NiCu，NiUO 2，NiVO和NiZn衍生物。第一种金属保留在配体的N 2 O 2隔室中，而第二种金属则占据O 2 O 2
• Unusual solvent-dependent syntheses of mononuclear and binuclear cobalt(II) complexes
  作者：Robert P. Kreh、Alfredo E. Rodriguez、Stephen P. Fox

  DOI：10.1039/c39840000130

  日期：——

  2-dimethyloctane-3,5,7-trione each provide two distinct binding sites for cobalt(II) ions, and in the presence of additional ligands (methanol, pyridine) mononuclear isomers with cobalt in the four-oxygen (O4) site are favoured while in the absence of these ligands, mononuclear isomers with cobalt in the N2O2site as well as a binuclear cobalt complex were isolated.

  1-苯基己烷-1,3,5-三酮和2,2-二甲基辛烷-3,5,7-三酮的乙二胺席夫碱衍生物各自为钴（II）离子提供了两个不同的结合位点偏爱在四氧（O 4）位具有钴的配体（甲醇，吡啶）单核异构体，而在没有这些配体的情况下，分离了在N 2 O 2位具有钴的单核异构体以及双核钴配合物。
• Kennedy, Brendan J.; McGrath, Anthony C.; Murray, Keith S., Inorganic Chemistry, 1987, vol. 26, # 4, p. 483 - 495
  作者：Kennedy, Brendan J.、McGrath, Anthony C.、Murray, Keith S.、Skelton, Brian W.、White, Allan H.

  DOI：——

  日期：——
• Epoxidation of cyclic olefins using dimeric molybdenum(VI) catalysts
  作者：M.L. D'Amico、K. Rasmussen、D. Sisneros、C. Magnussen、H. Wade、J.G. Russell、L.L. Borer

  DOI：10.1016/s0020-1693(00)93456-x

  日期：1992.1

  Catalytic properties of dimeric molybdenum(VI) triketonates were compared to those of MoO2(acac)2 in the epoxidation reaction of cyclooctene and 1,5-cyclooctadiene with tertiary butyl hydroperoxide. Studies of the reaction at a molar ratio of olefin:TBHP:catalyst = 1:1:0.001 for the monoolefin and 1:2:0.001 for the diolefin at 40 and 80-degrees-C in dichloroethane were carried out. The dimeric Mo(VI) complexes preferentially catalyzed the production of a monoepoxide.