5-(4′-(tetrazol-5″-yl)phenoxy) isophthalic acid | 1431524-24-1

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-(4′-(tetrazol-5″-yl)phenoxy) isophthalic acid
• 英文别名: 5-(4-(tetrazol-5-yl)phenoxy)isophthalic acid；5-(4-(Tetrazol-5-yl)phenoxy)isophthalic acid；5-[4-(2H-tetrazol-5-yl)phenoxy]benzene-1,3-dicarboxylic acid
• CAS: 1431524-24-1
• 化学式: C₁₅H₁₀N₄O₅
• 分子量: 326.268
• InChiKey: HZSXHUMSEBVNCC-UHFFFAOYSA-N

物化性质

• 沸点：
  651.8±65.0 °C(Predicted)
• 密度：
  1.565±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  24
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  138
• 氢给体数：
  3
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  cadmium(II) nitrate tetrhydrate 、 5-(4′-(tetrazol-5″-yl)phenoxy) isophthalic acid 在 sodium hydroxide 作用下， 以 水 为溶剂， 反应 96.0h， 以70%的产率得到[Cd(5-(4′-(tetrazol-5″-yl)phenoxy) isophthalic acid-2H)]_n
  参考文献：
  名称：

  Two new three-dimensional metal–organic frameworks constructed from a semirigid V-shaped ligand with luminescent and topology studies

  摘要：

  Two new compounds [Zn2L(OH)H2O](n) (1) and [Cd(HL)](n) (2) have been assembled from a semirigid V-shape ligand under hydrothermal conditions. The two compounds were determined by single-crystal X-ray diffraction analyses and further characterized by solid state emission spectra, IR spectra, and thermogravimetric analyses. Single crystal X-ray diffraction analyses show that both of the two compounds crystallize in space group P (1) over bar and display a three-dimensional (3D) structure with different topologies of fluorite topology for 1 and Au4Ho topology for 2. It is noteworthing that 1 has a novel Zn-2 dinuclear unit containing only one bridging oxygen atom between two Zn atoms. Studies of photophysical properties reveal that 1 and 2 present luminescence, which can be ascribed to the emission of intraligand transition. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.01.015

文献信息

• Excitation wavelength-induced color-tunable and white-light emissions in lanthanide(<scp>iii</scp>) coordination polymers constructed using an environment-dependent luminescent tetrazolate–dicarboxylate ligand
  作者：Yu Xiao、Shuai-Hua Wang、Fa-Kun Zheng、Mei-Feng Wu、Ju Xu、Zhi-Fa Liu、Jun Chen、Rong Li、Guo-Cong Guo

  DOI：10.1039/c5ce02140e

  日期：——

  Color-tunable and white-light emitting lanthanide(iii) polymers with a selective light-emitting ligand have been constructed.

  构建了具有可调颜色和白光发射的镧系（iii）聚合物，具有选择性发光配体。