2,9-bis(methoxymethyl)-2,9-dimethyl-4,7-dioxadecane-1,10-diol | 78385-27-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,9-bis(methoxymethyl)-2,9-dimethyl-4,7-dioxadecane-1,10-diol
• 英文别名: 3-[2-(2-hydroxymethyl-3-methoxy-2-methyl-propoxy)-ethoxy]-2-methoxymethyl-2-methyl-propan-1-ol；2-[2-[2-(Hydroxymethyl)-3-methoxy-2-methylpropoxy]ethoxymethyl]-3-methoxy-2-methylpropan-1-ol
• CAS: 78385-27-0
• 化学式: C₁₄H₃₀O₆
• 分子量: 294.389
• InChiKey: WBLUWKNWRVKMAU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.4
• 重原子数：
  20
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  77.4
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,9-bis(methoxymethyl)-2,9-dimethyl-4,7-dioxadecane-1,10-diol 在 硝酸 、 sodium nitrite 作用下， 以22 g的产率得到2,9-bis(methoxymethyl)-2,9-dimethyl-4,7-dioxadecanedioic acid
  参考文献：
  名称：

  2,9-双（甲氧基甲基）-2,9-二甲基-4,7-二氧十二烷二酸和2,2,9,9-四甲基-4,7-二硫十二烷二酸的大环铜（II）螯合物。[2,9-双（甲氧基甲基）-2,9-二甲基-4,7-二氧杂环十二烷]铜（II）的水，吡啶和三苯基膦加合物的晶体和分子结构

  摘要：

  据报道，以非对映异构体的混合物形式制备2,9-双（甲氧基甲基）-2,9-二甲基-4,7-二氧十二烷二甲酸（1; H 2 Y），并将其转化为大环的，羧酸盐桥接的，二聚铜（II）衍生物[{CuYL} 2 ] [L =水（2），没有配体（3），吡啶（4）或三苯膦（5）]。这些都以两种形式获得，即（2a）-（5a），其中羧酸盐配体以DL和内消旋形式存在，而（2b）-（5b）仅包含内消旋形式。讨论了光谱数据（红外和紫外可见）。由衍射仪数据确定了在三斜晶空间群中结晶的化合物（2a），（4b）和（5b）的结构P，Z =1。晶胞尺寸为：a = 11.506（4），b = 7.149（2），c = 13.085（3）Å，α= 101.01（1），β= 114.06（2），γ = 90.85 （2a）为（2）°；一个= 11.230（4），b = 9.940（4），C ^ = 10.954（4），α= 112

  DOI：

  10.1039/dt9810001406
• 作为产物：
  描述：

  3-甲基-3-羟甲基氧杂环丁烷 在 亚磷酸三苯酯 、 N-溴代丁二酰亚胺(NBS) 、 硫酸 、 sodium 作用下， 以 甲醇 、 2-甲基-2-丁醇 、 二氯甲烷 为溶剂， 反应 30.0h， 生成 2,9-bis(methoxymethyl)-2,9-dimethyl-4,7-dioxadecane-1,10-diol
  参考文献：
  名称：

  2,9-双（甲氧基甲基）-2,9-二甲基-4,7-二氧十二烷二酸和2,2,9,9-四甲基-4,7-二硫十二烷二酸的大环铜（II）螯合物。[2,9-双（甲氧基甲基）-2,9-二甲基-4,7-二氧杂环十二烷]铜（II）的水，吡啶和三苯基膦加合物的晶体和分子结构

  摘要：

  据报道，以非对映异构体的混合物形式制备2,9-双（甲氧基甲基）-2,9-二甲基-4,7-二氧十二烷二甲酸（1; H 2 Y），并将其转化为大环的，羧酸盐桥接的，二聚铜（II）衍生物[{CuYL} 2 ] [L =水（2），没有配体（3），吡啶（4）或三苯膦（5）]。这些都以两种形式获得，即（2a）-（5a），其中羧酸盐配体以DL和内消旋形式存在，而（2b）-（5b）仅包含内消旋形式。讨论了光谱数据（红外和紫外可见）。由衍射仪数据确定了在三斜晶空间群中结晶的化合物（2a），（4b）和（5b）的结构P，Z =1。晶胞尺寸为：a = 11.506（4），b = 7.149（2），c = 13.085（3）Å，α= 101.01（1），β= 114.06（2），γ = 90.85 （2a）为（2）°；一个= 11.230（4），b = 9.940（4），C ^ = 10.954（4），α= 112

  DOI：

  10.1039/dt9810001406

文献信息

• IMAGE FORMING METHOD
  申请人：GOTOU Hiroshi

  公开号：US20130155145A1

  公开（公告）日：2013-06-20

  An image forming method applying a pretreatment liquid on the surface of a recording medium; and applying an inkjet ink including a colorant, a hydrosoluble organic solvent, a surfactant and water on the surface applied with the pretreatment liquid, wherein the hydrosoluble organic solvent includes at least one polyol including an equilibrium water content in an amount not less than 30% by weight at 23° C. and 80% RH; an amide compound having the following formula (I); and at least one of compounds having the following formulae (II) to (IV), and wherein a pure water transfers to the recording medium in an amount of from 1 to 15 mL/m 2 when measured by a dynamic scanning liquid absorptometer at a contact time of 100 ms.

  一种图像形成方法，其在记录介质的表面上应用预处理液，并在应用预处理液的表面上应用包括颜料、水溶性有机溶剂、表面活性剂和水的喷墨墨水，其中水溶性有机溶剂包括至少一种多元醇，其在23℃和80%相对湿度下的平衡含水量不少于30%（重量百分比），具有以下式（I）的酰胺化合物，以及具有以下式（II）至（IV）之一的化合物，其中在100ms接触时间下，通过动态扫描液体吸收计测量，纯水向记录介质转移的量为1至15 mL/m2。
• RECORDING INK AS WELL AS INK MEDIA SET, INK CARTRIDGE, INK RECORDED MATTER, INKJET RECORDING APPARATUS AND INKJET RECORDING METHOD
  申请人：Aruga Tamotsu

  公开号：US20070197685A1

  公开（公告）日：2007-08-23

  A recording ink containing at least a solid component which contains a colorant and a resin and is a solid at 25° C., a liquid component which has a higher boiling point than that of water and is a liquid at 25° C. and water, wherein the total content of the liquid component in the recording ink is 20% by mass or less, the total content of the solid component in the recording ink is 20% by mass or more, and the total content of a resin component in the solid component is 40% by mass to 95% by mass relative to a total amount of the solid component is provided.
• RECORDING INK, INK CARTRIDGE, INKJET RECORDING METHOD, AND INKJET RECORDING APPARATUS
  申请人：Goto Hiroshi

  公开号：US20090098312A1

  公开（公告）日：2009-04-16

  The present invention provides a recording ink including a composite pigment particle, a water-soluble solvent, and water, wherein the composite pigment particle is a primary particle coated with a coating resin, wherein the primary particle is a white pigment on the surface of which an oil-soluble dye is adsorbed or attached. In one aspect, the white pigment is preferably at least one selected from a white inorganic pigment, a pearl pigment, and an extender pigment, in another aspect, the coating resin is preferably one of a (meth)acrylic resin, a polyester resin, and a polyurethane resin, wherein the acid value of the coating resin is from 50 mgKOH/g to 250 mgKOH/g, and in another aspect, an average particle diameter (D50%) of the composite pigment particle is preferably 150 nm or less.
• RECORDING INK, INK MEDIA SET, INK CARTRIDGE, INK RECORDED MATTER, INKJET RECORDING APPARATUS, AND INKJET RECORDING METHOD
  申请人：Morohoshi Naoya

  公开号：US20090162569A1

  公开（公告）日：2009-06-25

  There is provided a recording ink containing: solid constituents, which contain a colorant and a resin, and stay solid in the ink having a temperature of 25° C.; liquid constituents, which have a higher boiling point than a boiling point of water, and stay liquid in the ink having a temperature of 25° C.; and water, wherein a total amount of the solid constituents in the recording ink is in the range of 2.0% by mass or more to less than 20% by mass, wherein a ratio A/B of a total amount of the liquid constituents in the recording ink A to the total amount of the solid constituents in the recording ink B is from 0.70 to 1.75, and wherein the viscosity of the recording ink at 25° C. is 10 mPa s or less.
• Pigment Dispersion, Recording Ink, Ink Cartridge, Ink-Jet Recording Method and Ink-Jet Recording Apparatus
  申请人：Goto Hiroshi

  公开号：US20090176070A1

  公开（公告）日：2009-07-09

  A pigment dispersion is provided that includes a pigment, a pigment dispersant, a polymer dispersion stabilizer and water, wherein the polymer dispersion stabilizer is an alpha-olefin/maleic anhydride copolymer expressed by the formula (1) below. A recording ink is also provided that includes the pigment dispersion, a surfactant, a water-dispersible resin, a humectant and water. In the structural formula (1), R represents an alkyl group and n is an integer of 30 to 100.