bis[μ2-O[(E)-2-[(2-oxyphenyl)methylene]hydrazine-N-phenylcarbothioamide-κ3-O,N,S][acetate-κ-O]zinc(II)] | 1358772-01-6

• 英文名称: bis[μ2-O[(E)-2-[(2-oxyphenyl)methylene]hydrazine-N-phenylcarbothioamide-κ3-O,N,S][acetate-κ-O]zinc(II)]
• CAS: 1358772-01-6
• 化学式: C₃₂H₃₀N₆O₆S₂Zn₂
• 分子量: 789.539
• InChiKey: YJPPGRMUFGYKIX-YUKGCYECSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-hydroxybenzaldehyde 4-phenylthiosemicarbazone 、 zinc(II) acetate dihydrate 、 溶剂黄146 以 乙醇 为溶剂， 以89%的产率得到bis[μ2-O[(E)-2-[(2-oxyphenyl)methylene]hydrazine-N-phenylcarbothioamide-κ3-O,N,S][acetate-κ-O]zinc(II)]
  参考文献：
  名称：

  Synthesis, structural and spectral characterization of Zn(II) complexes, derived from thiourea and thiosemicarbazide

  摘要：

  Novel mono-and binuclear complexes of Zn(II) with thiourea derivatives (H2L) (N-2-propenyl-N'-2-pyridinylthiourea) and thiosemicarbazide, H3L (2-[(2-hydroxyphenyl)methylene]hydrazine-N-(2-propenyl)carbothioamide, (2-[(2-hydroxyphenyl) methylene] hydrazine-N-phenylcarbothioamide) have been synthesized. The possibility of mono-or tridentate coordination to the central metal ion of these ligands both in neutral and in monodeprotonated thionic tautomeric form with the stoichiometric ratios Zn: L = 1: 1 and 1: 2 has been shown. The synthesized complexes Zn(CH3COO)(2)(H2L)(2) (I), Zn-2(CH3COO)(2) (H2L)(2)center dot Zn-2(CH3COO)(H2O)(H2L)(2) (II), Zn(H2L)(2) (III), Zn-2(CH3COO)(2)(H2L)(2) (IV) have been studied by IR, UV-Vis, H-1, C-13 NMR spectroscopy and single crystal X-ray diffraction (I, II, IV). It has been established that in compound (I) the central Zn atom forms a strongly distorted tetrahedral ZnS2O2 coordination, while in (II) and (IV) it forms a square-pyramidal ZnSNO3 environment. In the case of complex (II) the asymmetric unit contains two molecules of binuclear complex compounds, which are slightly differ by coordination in vertex direction of Zn polyhedron. The square-pyramidal geometry of Zn(II) ions from the first molecule completed by two acetate anions, which is similar to compound (IV). In the second molecule, the Zn(II) coordination polyhedrons are completed by one acetate anion and one water molecule. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.10.027