4-{[(S)-2-methylbutyl]sulfonyl}aminobenzene | 471243-45-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-{[(S)-2-methylbutyl]sulfonyl}aminobenzene
• CAS: 471243-45-5
• 化学式: C₁₁H₁₇NO₂S
• 分子量: 227.327
• InChiKey: IXGFGVOKZHEUKB-VIFPVBQESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.09
• 重原子数：
  15.0
• 可旋转键数：
  4.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  60.16
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  4-{[(S)-2-methylbutyl]sulfonyl}aminobenzene 在 盐酸 、 potassium carbonate 、 sodium nitrite 作用下， 以 水 、 丙酮 为溶剂， 反应 2.0h， 生成 4-(8-hydroxyoctyloxy)-4'-{[(S)-2-methylbutyl]sulfonyl}azobenzene
  参考文献：
  名称：

  Photorefractive Effect of Liquid Crystalline Polymers Possessing Azobenzene Chromophores

  摘要：

  A series of liquid crystalline polymers possessing azobenzene chromophores were synthesized, and in each polymer the photorefractive effect of the isotropic phase was investigated. The photorefractive effect was evaluated by a four-wave mixing experiment. The diffraction efficiency of a side-chain liquid crystalline polymer possessing chiral moieties was measured and compared with that of a polymer possessing achiral chromophores. Chiral polymers exhibited unusual electric-field dependence on diffraction efficiency. The effects of liquid crystallinity and chiral substituents on photorefractivity are discussed.

  DOI：

  10.1080/10587250210541
• 作为产物：
  描述：

  (S)-(+)-1-氯-2-甲基丁烷 在 Pt/Al₂O₃ sodium tungstate 、 氢气 、 双氧水 、 potassium carbonate 、 potassium iodide 作用下， 以 甲醇 、 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 16.0h， 生成 4-{[(S)-2-methylbutyl]sulfonyl}aminobenzene
  参考文献：
  名称：

  Photorefractive Effect of Liquid Crystalline Polymers Possessing Azobenzene Chromophores

  摘要：

  A series of liquid crystalline polymers possessing azobenzene chromophores were synthesized, and in each polymer the photorefractive effect of the isotropic phase was investigated. The photorefractive effect was evaluated by a four-wave mixing experiment. The diffraction efficiency of a side-chain liquid crystalline polymer possessing chiral moieties was measured and compared with that of a polymer possessing achiral chromophores. Chiral polymers exhibited unusual electric-field dependence on diffraction efficiency. The effects of liquid crystallinity and chiral substituents on photorefractivity are discussed.

  DOI：

  10.1080/10587250210541