2-<(p-Tetrahydropyranyloxymethyl)phenyl>-1,10-phenanthroline | 157523-08-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 2-<(p-Tetrahydropyranyloxymethyl)phenyl>-1,10-phenanthroline
• CAS: 157523-08-5
• 化学式: C₂₄H₂₂N₂O₂
• 分子量: 370.451
• InChiKey: HAVDTAUUSROZAG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.49
• 重原子数：
  28.0
• 可旋转键数：
  4.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  44.24
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  2-<(p-Tetrahydropyranyloxymethyl)phenyl>-1,10-phenanthroline 在 正丁基锂 、 对甲苯磺酸 作用下， 以 乙醚 、 乙醇 为溶剂， 反应 8.0h， 生成 2,9-bis(p-hydroxymethylphenyl)-1,10-phenanthroline
  参考文献：
  名称：

  Spectral sensitization of large-band-gap semiconductors (thin films and ceramics) by a carboxylated bis(1,10-phenanthroline)copper(I) complex

  摘要：

  Photoelectrochemical cells based on colloidal films of titanium dioxide and zinc oxide ceramic electrodes sensitized by a bis(2,9-diphenyl-1,10-phenanthroline)copper(i) complex modified at the para positions with NaO2C groups, were investigated in an aqueous medium using hydroquinone as electron donor. The sensitizing effect is greater with the films due to the enhanced geometric area projection. The photocurrent-action spectrum obtained with this complex covers almost the whole of the solar visible region. The quantum efficiency was found to depend on the degree of surface coverage by the complex. In a solar-cell arrangement the open-circuit photovoltage was 0.6 V with a small short-circuit photocurrent of ca. 0.6 mA cm-2 in iodide-containing propylene carbonate.

  DOI：

  10.1039/dt9940001649
• 作为产物：
  描述：

  1,10-菲罗啉 、 2-((4-bromobenzyl)oxy)tetrahydro-2H-pyran 在 正丁基锂 作用下， 以 乙醚 为溶剂， 以68%的产率得到2-<(p-Tetrahydropyranyloxymethyl)phenyl>-1,10-phenanthroline
  参考文献：
  名称：

  Spectral sensitization of large-band-gap semiconductors (thin films and ceramics) by a carboxylated bis(1,10-phenanthroline)copper(I) complex

  摘要：

  Photoelectrochemical cells based on colloidal films of titanium dioxide and zinc oxide ceramic electrodes sensitized by a bis(2,9-diphenyl-1,10-phenanthroline)copper(i) complex modified at the para positions with NaO2C groups, were investigated in an aqueous medium using hydroquinone as electron donor. The sensitizing effect is greater with the films due to the enhanced geometric area projection. The photocurrent-action spectrum obtained with this complex covers almost the whole of the solar visible region. The quantum efficiency was found to depend on the degree of surface coverage by the complex. In a solar-cell arrangement the open-circuit photovoltage was 0.6 V with a small short-circuit photocurrent of ca. 0.6 mA cm-2 in iodide-containing propylene carbonate.

  DOI：

  10.1039/dt9940001649