(1S,1aS,1bR,5aS,6aS)-1-Isopropyl-5a-methyl-2-methylene-octahydro-cyclopropa[a]inden-5-one | 84071-86-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (1S,1aS,1bR,5aS,6aS)-1-Isopropyl-5a-methyl-2-methylene-octahydro-cyclopropa[a]inden-5-one
• CAS: 84071-86-3
• 化学式: C₁₅H₂₂O
• 分子量: 218.339
• InChiKey: JTRIBZLRPLDRMQ-MFGQWXODSA-N

反应信息

• 作为产物：
  描述：

  torilenol 在 chromium(VI) oxide 作用下， 以 吡啶 为溶剂， 反应 5.0h， 以50%的产率得到(1S,1aS,1bR,5aS,6aS)-1-Isopropyl-5a-methyl-2-methylene-octahydro-cyclopropa[a]inden-5-one
  参考文献：
  名称：

  BIOMIMETIC CONVERSION OF EPOXYGERMACRENE-D TO A NOVEL SESQUITERPENE OF THE PLANTTORILIS JAPONICADC.

  摘要：

  Epoxygermacrene-D was treated with basic alumina to afford a new type of sesquiterpene, whose stereostructure was determined on the basis of its spectral data coupled with an X-ray crystallographic analysis of the corresponding ketone produced on CrO3 oxidation.

  DOI：

  10.1246/cl.1982.1681