| 178542-79-5

• CAS: 178542-79-5
• 化学式: C₂₄H₃₂FeNReSe₂
• 分子量: 734.499
• InChiKey: QPTTUEKKLJRJED-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dilithium ferrocene diselenolato * 2 tetrahydrofuran 、 (tert-butylimido)dichloro(η5-pentamethylcyclopentadienyl)rhenium(V) 以 四氢呋喃 为溶剂， 以38.1%的产率得到
  参考文献：
  名称：

  Rhenium complexes containing 1,1′-ferrocene dithiolato and diselenolato chelate ligands

  摘要：

  The reactions of the rhenium(V) dihalides TpRe(O)Cl-2, Cp*Re(O)Cl-2 and Cp*Re(N(t)Bu)Cl-2 with the dilithium derivative of 1,1'-ferrocene dithiol and diselenol, respectively, have been used to prepare heterodimetallic complexes which contain both rhenium (in the center of a half-sandwich complex) and iron (in the sandwich cage). The six new complexes were characterized by IR, H-1 and C-13 NMR spectroscopy and by EI mass spectrometry. The molecular structure of TpRe(O)[S(2)fc] (1a) was determined by X-ray crystallography which revealed a long non-bonding distance (438.9 pm) between the two metals. (Abbreviations: Cp* = eta(5)-pentamethylcyclopentadienyl, eta(5)-C(5)Me(5); Tp = hydrido-tris(1-pyrazolyl)borate, HB(C3H3N2)(3); Tp* = hydrido-tris(3,5-dimethyl-1-pyrazolyl) borate, HB(C3H(Me(2))N-2)(3); fc = 1,1'-ferrocenylene, Fe(C5H4-)(2); (t)Bu = tert-butyl, C4H9-.)..

  DOI：

  10.1016/0022-328x(95)05889-w