2,4-dichloro-9-methoxy-7,7-dimethyl-7H-benzo[c]fluoren-5-yl acetate | 1309957-41-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 2,4-dichloro-9-methoxy-7,7-dimethyl-7H-benzo[c]fluoren-5-yl acetate
• 英文别名: (2,4-Dichloro-9-methoxy-7,7-dimethylbenzo[c]fluoren-5-yl) acetate
• CAS: 1309957-41-2
• 化学式: C₂₂H₁₈Cl₂O₃
• 分子量: 401.289
• InChiKey: UKDYDFVITKCZFX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  27
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,4-dichloro-9-methoxy-7,7-dimethyl-7H-benzo[c]fluoren-5-yl acetate 在 四(三苯基膦)钯 N-溴代丁二酰亚胺(NBS) 、 sodium carbonate 、 对甲苯磺酸 作用下， 以 四氢呋喃 、 水 、 1,2-二氯乙烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 31.17h， 生成 3-(4-butoxyphenyl)-3-(4-methoxyphenyl)-10-[4-(4-(4-(4-trans-pentylcyclohexyl)phenyl)benzamido)phenyl]-5,7-dichloro-11-methoxy-13,13-dimethyl-3H,13H-indeno[2',3':3,4]naphtho[1,2-b]pyran
  参考文献：
  名称：

  LACTONE COMPOUNDS AND MATERIALS MADE THEREFROM

  摘要：

  本发明涉及以下I和II式所代表的内酯化合物及其制备方法。本发明还涉及从这些内酯化合物制备其他材料的方法，例如融合环吲哚酚化合物（例如吲哚融合萘酚）和融合环吲哚吡喃化合物（例如吲哚融合萘吡喃）。

  公开号：

  US20120157677A1

文献信息

• INDENO- FUSED RING COMPOUNDS HAVING PHOTOCHROMIC PROPERTIES
  申请人：Transitions Optical, Inc.

  公开号：EP2651913A1

  公开（公告）日：2013-10-23
• PHOTOCHROMIC COMPOUNDS AND COMPOSITIONS
  申请人：Transitions Optical, Inc.

  公开号：EP2652552B9

  公开（公告）日：2016-02-17
• INDENO-FUSED RING COMPOUNDS HAVING PHOTOCHROMIC PROPERTIES
  申请人：Transitions Optical, Inc.

  公开号：EP2651913B1

  公开（公告）日：2017-04-19
• Photochromic compounds and compositions
  申请人：He Meng

  公开号：US20110129678A1

  公开（公告）日：2011-06-02

  Described herein are compounds generally comprising an indeno[2′,3′:3,4]naptho[1,2-b]pyran structure. Such compounds may be useful for their photochromic properties, and be used in certain photochromic compositions. Such compositions may further comprise other photochromic compositions and/or materials. Additionally, such compounds and/or compositions may be suitable for preparing certain photochromic articles. Also described herein are methods for preparing certain photochromic compounds, compositions, and articles.
• Indeno-fused ring compounds
  申请人：He Meng

  公开号：US20110140056A1

  公开（公告）日：2011-06-16

  The present invention relates to compounds represented by the following Formulas (I) and (II), Ring-A of Formulas I and II can be, for example, an aryl group, and Q′ and Q′″ can each be independently selected from groups, such as, halogen, —OH, —CN, amine groups, amide groups, carboxylic acid ester groups, carboxylic acid groups, alkenyl groups, alkynyl groups, carbonate groups, sulfide groups, and sulfonic acid ester groups. The present invention also relates to photochromic compositions and photochromic articles that include one or more photochromic compounds, such as represented by Formula II.