| 1119276-02-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1119276-02-6
• 化学式: C₄₃H₄₈O₉
• 分子量: 708.849
• InChiKey: HWHOIBCIRHSEQP-ZBIQRMRKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.13
• 重原子数：
  52.0
• 可旋转键数：
  15.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  83.07
• 氢给体数：
  0.0
• 氢受体数：
  9.0

反应信息

• 作为反应物：
  描述：

  、 乙硫醇 在 ammonium cerium (IV) nitrate 作用下， 以 乙腈 为溶剂， 反应 16.25h， 以40%的产率得到ethyl 3,6-di-O-benzyl-4-O-(2,3-di-O-benzyl-α-D-glucopyranosyl)-2-deoxy-1-thio-β-D-arabino-hexopyranoside
  参考文献：
  名称：

  Synthesis of 2-deoxy cyclic and linear oligosaccharides by oligomerization of monomers

  摘要：

  Cyclic and linear oligosaccharides constituted with 2-deoxy sugar units are synthesized by an oligomerization reaction involving activated thioglycoside monomers, consisting of a 2-deoxy sugar unit. The oligomerization promoter plays an important role in the formation of either the cyclic- or the linear oligosaccharides. Encapsulation abilities of a 2-deoxy cyclic hexamer with p-nitrophenot, by a H-1 NMR method, showed complexation of the guest molecule with the host molecule. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2008.10.026
• 作为产物：
  描述：

  、 溴甲苯 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 、 mineral oil 为溶剂， 反应 4.0h， 以75%的产率得到
  参考文献：
  名称：

  Synthesis of 2-deoxy cyclic and linear oligosaccharides by oligomerization of monomers

  摘要：

  Cyclic and linear oligosaccharides constituted with 2-deoxy sugar units are synthesized by an oligomerization reaction involving activated thioglycoside monomers, consisting of a 2-deoxy sugar unit. The oligomerization promoter plays an important role in the formation of either the cyclic- or the linear oligosaccharides. Encapsulation abilities of a 2-deoxy cyclic hexamer with p-nitrophenot, by a H-1 NMR method, showed complexation of the guest molecule with the host molecule. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2008.10.026