[1,5-C10H6(OCH2CH2O2CCHSAu)2(μ-Ph2P(CH2)4PPh2)] | 909123-02-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [1,5-C10H6(OCH2CH2O2CCHSAu)2(μ-Ph2P(CH2)4PPh2)]
• CAS: 909123-02-0
• 化学式: C₄₆H₄₆Au₂O₆P₂S₂
• 分子量: 1214.88
• InChiKey: SJLWZSUGYDOTAE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  7.81
• 重原子数：
  58.0
• 可旋转键数：
  4.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  71.06
• 氢给体数：
  0.0
• 氢受体数：
  8.0

反应信息

• 作为产物：
  描述：

  1,4-双(二苯基膦)丁烷 以 甲醇 、 二氯甲烷 为溶剂， 生成 [1,5-C10H6(OCH2CH2O2CCHSAu)2(μ-Ph2P(CH2)4PPh2)]
  参考文献：
  名称：

  Polymeric and macrocyclic gold(I) complexes with bridging dithiolate and diphosphine ligands

  摘要：

  The reaction of digold(I) diphosphine complexes [Au-2(O2CCF3)(2)(mu-Ph2P-X-PPh2)] with dithiols HS-Y-SH can give either macrocyclic complexes [Au-2(mu-S-Y-S)(mu-Ph2P-X-PPh2)] or polymeric complexes [Au-2(mu-S-Y-S)(mu-Ph2P-X-PPh2)](n). The structures of the macrocyclic complex [Au-2{mu-(S-4-C6H4)(2)S} {mu-Ph2P(CH2)(4)PPh2}], and the polymeric complexes [Au-n{mu-(S-CH2CO2CH2CH2O)(2)-1,-4C(6)H(4)}(n)(mu-trans-Ph2PCH=CHPPh2)(n)] and [Au-n{mu-(S-CH2CO2CH2CH2O)(2)-1,5-C10H6}(n)(mu-trans-Ph2PCH=CHPPh2)(n)] have been determined. Evidence is presented that the complexes exist primarily as macrocycles in solution and that, in favorable cases, ring-opening polymerization occurs during crystallization. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.01.018