(E)-3-phenyl-1-[4-[[1-[3-[4-[[4-[(E)-3-phenylprop-2-enoyl]phenoxy]methyl]triazol-1-yl]-2,2-bis[[4-[[4-[(E)-3-phenylprop-2-enoyl]phenoxy]methyl]triazol-1-yl]methyl]propyl]triazol-4-yl]methoxy]phenyl]prop-2-en-1-one | 1196532-69-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 英文名称: (E)-3-phenyl-1-[4-[[1-[3-[4-[[4-[(E)-3-phenylprop-2-enoyl]phenoxy]methyl]triazol-1-yl]-2,2-bis[[4-[[4-[(E)-3-phenylprop-2-enoyl]phenoxy]methyl]triazol-1-yl]methyl]propyl]triazol-4-yl]methoxy]phenyl]prop-2-en-1-one
• CAS: 1196532-69-0
• 化学式: C₇₇H₆₄N₁₂O₈
• 分子量: 1285.43
• InChiKey: NDVDYRWNJYMRNK-BWURDYBPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11
• 重原子数：
  97
• 可旋转键数：
  32
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  228
• 氢给体数：
  0
• 氢受体数：
  16

反应信息

• 作为产物：
  描述：

  (E)-3-phenyl-1-(4-(prop-2-yn-1-yloxy)phenyl)prop-2-en-1-one 、 1,3-diazido-2,2-bis(azidomethyl)propane 在 copper(ll) sulfate pentahydrate 、 (+)-sodium-L-ascorbate 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 12.0h， 以63%的产率得到(E)-3-phenyl-1-[4-[[1-[3-[4-[[4-[(E)-3-phenylprop-2-enoyl]phenoxy]methyl]triazol-1-yl]-2,2-bis[[4-[[4-[(E)-3-phenylprop-2-enoyl]phenoxy]methyl]triazol-1-yl]methyl]propyl]triazol-4-yl]methoxy]phenyl]prop-2-en-1-one
  参考文献：
  名称：

  Synthesis and Characterization of Some Novel Dendritic Architectures Bearing Chalcone at the Periphery Through Click Approach

  摘要：

  Synthesis of 1,2,3-triazole-based dendritic architectures bearing a chalcone unit at the surface group has been achieved through a click reaction by the convergent synthetic strategy, in which tri- and tetra-azide were used as core units.

  DOI：

  10.1080/00397910902840827

文献信息

• Synthesis and Characterization of Some Novel Dendritic Architectures Bearing Chalcone at the Periphery Through Click Approach
  作者：Perumal Rajakumar、Sebastian Raja

  DOI：10.1080/00397910902840827

  日期：2009.10.12

  Synthesis of 1,2,3-triazole-based dendritic architectures bearing a chalcone unit at the surface group has been achieved through a click reaction by the convergent synthetic strategy, in which tri- and tetra-azide were used as core units.