The present invention is to provide a process for preparing a highly polymerized aromatic polycarbonate resin, which comprises the steps of a highly polymerizing step for reacting an aromatic polycarbonate prepolymer and an aliphatic diol compound in the presence of a transesterification catalyst to obtain a highly polymerized aromatic polycarbonate resin, a cyclic carbonate removal step for removing at least part of the cyclic carbonate by-produced in the above highly polymerizing step out of the reaction system, and a recycle step of hydrolyzing the cyclic carbonate removed in the cyclic carbonate removal step to obtain an aliphatic diol compound and using the obtained aliphatic diol compound as at least a part of the aliphatic diol compound to be used in the highly polymerizing step.
本发明旨在提供一种制备高度聚合的芳香族聚
碳酸酯
树脂的工艺,该工艺包括以下步骤 一高度聚合步骤,在酯交换催化剂存在下,使芳香族聚
碳酸酯预聚物和脂肪族二元醇化合物发生反应,得到高度聚合的芳香族聚
碳酸酯
树脂、环状
碳酸酯去除步骤,用于将上述高聚合步骤中产生的至少部分环状
碳酸酯从反应体系中去除,以及循环步骤,用于
水解环状
碳酸酯去除步骤中去除的环状
碳酸酯,以获得脂肪族二元醇化合物,并将获得的脂肪族二元醇化合物用作高聚合步骤中使用的至少部分脂肪族二元醇化合物。