[Ni(ochapim)2] | 57377-56-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: [Ni(ochapim)2]
• 英文别名: [bis(2-hydroxyacetophenamine)nickel(II)]；2-ethanimidoylphenolate;nickel(2+)
• CAS: 57377-56-7；26692-41-1
• 化学式: C₁₆H₁₆N₂NiO₂
• 分子量: 327.005
• InChiKey: YHRFYTAUAWIFHR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ni(ochapim)2] 在 sodium acetate 作用下， 以 乙醇 、 氯仿 、 水 为溶剂， 生成 bis{1-(2-hydroxy-3,5-dibromophenyl)ethylideneoxime}Ni(II)
  参考文献：
  名称：

  Thaker B. T., Journal of the Indian Chemical Society, 1984, vol. 61, p. 258 - 260

  摘要：

  DOI：
• 作为产物：
  描述：

  生成 [Ni(ochapim)2]
  参考文献：
  名称：

  Pfeiffer, P.; Buchholz, E.; Bauer, O., Journal fuer Praktische Chemie (Leipzig), 1931, vol. 129, # 2, p. 163 - 177

  摘要：

  DOI：

文献信息

• Synthesis, characterization, and X-ray crystal structures of copper(II) and nickel(II) complexes with Schiff base
  作者：H. Y. Liu

  DOI：10.1134/s1070328413070063

  日期：2013.8

  In the crystal structure of I, the perchlorate anions are linked to the dinuclear copper(II) complex cations through intermolecular N-H...O hydrogen bonds. In the crystal structure of II, the mononuclear nickel complex molecules are linked through intermolecular N-H...O hydrogen bonds, forming a trimer.

  新的铜（II）配合物，[Cu 2 L 1 L 2 ]·ClO 4（I）和[Ni（L 3）2 ]（II），其中L 1是2- [1-（2-制备并表征了L 2为N，N'-乙烯-双（2-羟基乙酰苯甲叉亚胺）的双阴离子形式，L 3为2-（1-亚氨基乙基）苯酚的单阴离子形式。元素分析，FT-IR光谱和X射线单晶衍射。在络合物I中，Cu（1）原子由NNO三齿配体L 1和L的两个酚O原子配位如图2所示，形成方形的金字塔形几何形状。络合物I中的Cu（2）原子由NNOO四齿配体L 2配位，形成方形平面几何形状。配合物II中的Ni原子与来自两个配体L 3的两个酚盐O和两个亚胺N原子配位，形成方形平面几何形状。在I的晶体结构中，高氯酸根阴离子通过分子间的NH ... O氢键与双核铜（II）络合物阳离子连接。在II的晶体结构中，单核镍配合物分子通过分子间的NH ... O氢键连接，形成三聚体。
• Interaction of amines and some nickel (II) Schiff-base compounds—I
  作者：E.J. Olszewski、D.F. Martin

  DOI：10.1016/0022-1902(65)80349-9

  日期：1965.2

  (II) ion, substituted salicylaldehydes, and various amines, and effectiveness of the method is discussed with respect to preparation of the Schiff-base ligands and nickel (II) Schiff-base compounds. Amine exchange as a method of preparation is discussed and compared with the method of direct amine addition to bis(salicylaldehydo)nickel (II). Some new Schiff-base compounds of nickel (II) are reported

  考虑到镍（II）离子，取代的水杨醛和各种胺的镍（II）Schiff碱化合物的原位制备范围，并且讨论了有关Schiff碱配体的制备方法的有效性和镍（II）席夫碱化合物。讨论了将胺交换作为一种制备方法，并将其与将胺直接添加到双（水杨醛醛）镍（II）中的方法进行了比较。报道并表征了一些新的席夫碱镍（II）化合物。描述了异常胺交换的几个例子，这些例子涉及氯仿溶剂的脱卤作用。
• Syntheses and Crystal Structures of Copper(II) and Nickel(II) Complexes With Schiff Bases: Nickel(II) Induced Cleavage of the C–N Bonds
  作者：Shao-Song Qian、Dong-Mei Xian、Zhong-Lu You、Hai-Liang Zhu

  DOI：10.1080/15533174.2012.752389

  日期：2013.9.14

  Three centrosymmetric mononuclear copper(II) and nickel(II) complexes, [Cu(MMP)2] (1), [Ni(IMP)2] (2), and [Ni(IEP)2] (3) (MMP = 5-methoxy-2-[(2-morpholin-4-ylethylimino)methyl] phenolate, IMP = 2-iminomethyl-5-methoxyphenolate, IEP = 2-(1-iminoethyl)phenolate), have been prepared from similar tridentate Schiff bases derived from 2-morpholin-4-ylethylamine with 4-methoxysalicylaldehyde and 2-acetylphenol

  三种中心对称单核铜（II）和镍（II）配合物[Cu（MMP）2 ]（1），[Ni（IMP）2 ]（2）和[Ni（IEP）2 ]（3）（MMP = 5-甲氧基-2-[（（2-吗啉-4-基乙基亚氨基）甲基]酚盐，IMP = 2-亚氨基甲基-5-甲氧基苯酚盐，IEP = 2-（1-亚氨基乙基）酚盐，已由类似的三齿席夫碱制备由2-吗啉-4-基乙胺分别与4-甲氧基水杨醛和2-乙酰基苯酚衍生得到。通过元素分析，红外光谱和单晶X射线衍射对复合物进行表征。配合物中的Cu和Ni原子呈正方形平面配位。Ni 2+离子可能对席夫碱配体的C–N键的断裂起重要作用。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ni: MVol.C2, 7.12, page 724 - 733
  作者：

  DOI：——

  日期：——
• Precursor development, characterisation and evaluation of sublimation enthalpies of novel volatile complexes of nickel
  作者：S. Arockiasamy、C. Mallika、O.M. Sreetharan、V.S. Raghunathan、K.S. Nagaraja

  DOI：10.1016/j.ica.2008.09.023

  日期：2009.4

  The nickel complexes namely bis(2-hydroxyacetophenoato)nickel(II), Ni(ohap)(2) (1), bis(2-hydroxyacetophenamine) nickel(II), Ni(ohapim)(2) (2) and bis(2-hydroxypropiophenamine)nickel(II), Ni(ohppim)(2) (3) were synthesised in a systematic approach for the development of volatile nickel precursors for MOCVD. Upon screening these complexes by dynamic TG in an inert N-2 purge gas environment, only complexes 2 and 3 were found to be completely volatile by 363 and 373 degrees C, respectively. These two were further characterized by FT-IR, C, H, and N and FAB-mass spectrometry. The molecular masses of the predominant Ni bearing vapour species were found to be 326 and 355 Da for 2 and 3, respectively. The complex 3 was analysed by single crystal XRD, H-1 and C-13 NMR. The equilibrium vapour pressures (p(e)) of the precursors 2 and 3 over the temperature ranges of 486-581 and 443-552 K were determined by a TG-based transpiration technique, yielding values of 130.2 (+/- 7.2) and 113.3 (+/- 7.5) kJ mol (1), respectively, for their standard enthalpies of sublimation (Delta H-sub(0)). (c) 2008 Elsevier B.V. All rights reserved.