Lubricants and lubricating oils are provided which contain an oil-soluble copper-containing antioxidant and an oil-soluble dispersant prepared by a process which comprises (i) reacting at least one polyamine with at least one acyclic hydrocarbyl substituted succinic acylating agent in which the substituent contains an average of at least about 40 carbon atoms, and (ii) reacting the product so formed with a vicinal dicarboxylic acylating agent having 4 to about 30 carbon atoms in the molecule, the process being characterized in that in step (i) the acylating agent is reacted with the polyamine in a mole ratio of from 1.05 to about 2.85 moles of acylating agent per mole of polyamine, and in that in step (ii) the mole ratio of the vicinal dicarboxylic acylating agent is from 0.10 to 2.50 moles per mole of said polyamine with the proviso that the total mole ratio of the acylating agents in (i) and (ii) per mole of said polyamine is at least 2.40. Such compositions exhibit enhanced compatibility toward fluoroelastomers while at the same time possess enhanced oxidative and thermal stability.
本发明提供了含有油溶性含
铜抗氧化剂和油溶性分散剂的润滑剂和润滑油,其制备工艺包括 (i) 至少一种
多胺与至少一种
无环烃基取代的琥珀酰化剂反应,其中取代基平均含有至少约 40 个
碳原子、和 (ii) 将这样形成的产物与分子中含有 4 至约 30 个
碳原子的烷基二
羧酸酰化 剂反应,该工艺的特征在于,在步骤(i)中,酰化剂与
多胺反应的摩尔比为 1.在步骤(ii)中,酰化剂的摩尔比为每摩尔所述
多胺 0.10 至 2.50 摩尔,但(i)和(ii)中酰化剂与每摩尔所述
多胺的总摩尔比至少为 2.40。此类组合物对
氟橡胶的相容性更强,同时具有更高的
氧化稳定性和热稳定性。