trideca-5,8-diyne | 67238-15-7

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: trideca-5,8-diyne
• 英文别名: Trideca-5,8-diin；5,8-Tridecadiyne
• CAS: 67238-15-7
• 化学式: C₁₃H₂₀
• 分子量: 176.302
• InChiKey: UEHFRYQTFMWJFR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  trideca-5,8-diyne 在 硫酸 、 mercury(II) oxide 作用下， 以 溶剂黄146 为溶剂， 生成 3-Butyl-2-propyl-2-cyclohexen-1-on
  参考文献：
  名称：

  1,4-Diketones from skipped acetylenes

  摘要：

  DOI：

  10.1021/jo00415a020
• 作为产物：
  描述：

  (hex-1-ynyl)magnesium bromide 在 乙醚 、 硫酸二甲酯 、 copper(l) chloride 作用下， 生成 trideca-5,8-diyne
  参考文献：
  名称：

  Some Formaldehyde Derivatives of Acetylenic Hydrocarbons¹

  摘要：

  DOI：

  10.1021/ja01250a017

文献信息

• Gold-Catalyzed Cascade Reaction of Skipped Diynes for the Construction of a Cyclohepta[<i>b</i>]pyrrole Scaffold
  作者：Naoka Hamada、Yusuke Yoshida、Shinya Oishi、Hiroaki Ohno

  DOI：10.1021/acs.orglett.7b01759

  日期：2017.7.21

  A gold-catalyzed cascade reaction of skipped diynes (1,4-diynes) and pyrroles has been developed. This reaction proceeds by the consecutive regioselective hydroarylation of two alkynes with a pyrrole, followed by a 7-endo-dig cyclization to give 1,6-dihydrocyclohepta[b]pyrroles in good yields. The direct synthesis of cyclohepta[b]indoles using indole nucleophiles has also been reported.

  已经开发了金催化的二炔（1,4-二炔）和吡咯的级联反应。该反应通过用吡咯连续进行两个炔烃的区域选择性加氢芳基化反应，然后进行7-内-挖-环化得到高收率的1,6-二氢环庚[ b ]吡咯。也已经报道了使用吲哚亲核试剂直接合成环庚[ b ]吲哚。
• 768. Studies with acetylenes. Part II. Some reactions of Grignard reagents with propargylic halides. Model linoleic and linolenic acid systems
  作者：S. S. Nigam、B. C. L. Weedon

  DOI：10.1039/jr9570003868

  日期：——
• Schlubach; Repenning, Justus Liebigs Annalen der Chemie, 1958, vol. 614, p. 37,46
  作者：Schlubach、Repenning

  DOI：——

  日期：——
• Copper-Catalyzed Electrophilic Amination of Alkenylzirconocenes with <i>O</i>-Benzoylhydroxylamines: An Efficient Method for Synthesis of Enamines
  作者：Xiaoyu Yan、Chao Chen、Yiqing Zhou、Chanjuan Xi

  DOI：10.1021/ol302004t

  日期：2012.9.21

  Copper-catalyzed electrophilic amination of alkenylzirconocenes is accomplished under mild reaction conditions. The reaction tolerates a wide range of functional groups and can be used to prepare some hindered enamines.
• Campo del Cielo iron meteorite: Sample shielding and meteoroid's preatmospheric size
  作者：R. G. LIBERMAN、J. O. FERNÁNDEZ NIELLO、M. L. TADA、L. K. FIFIELD、J. MASARIK、R. C. REEDY

  DOI：10.1111/j.1945-5100.2002.tb01111.x

  日期：2002.2

  Abstract— Long‐lived cosmogenic radioisotopes, 10Be, 26Al, 36Cl, 41Ca and 59Ni, have been measured in five samples from the Campo del Cielo iron meteorite by accelerator mass spectrometry (AMS). The 36Cl activities were significantly above the background. For the concentrations of the other four radioisotopes, only upper limits were obtained that were, however, consistent with the 36Cl result. The measured 36Cl activity allowed an estimate of the meteoroid's preatmospheric size: a radius larger than 300 cm and a mass of at least 840 000 kg. We conclude that this meteorite might be one of the largest meteorites to have been recovered.