N-[bis[(1,7,7-trimethyl-2-bicyclo[2.2.1]heptanyl)oxy]phosphanyl]-N-ethylethanamine;dichloropalladium | 213668-64-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: N-[bis[(1,7,7-trimethyl-2-bicyclo[2.2.1]heptanyl)oxy]phosphanyl]-N-ethylethanamine;dichloropalladium
• CAS: 213668-64-5
• 化学式: C₄₈H₈₈Cl₂N₂O₄P₂Pd
• 分子量: 996.511
• InChiKey: DGFJLLDGOLUQEB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  15.41
• 重原子数：
  59
• 可旋转键数：
  14
• 环数：
  8.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  dichloro(cycloocta-1,5-diene)palladium (II) 、 N-[bis[(1,7,7-trimethyl-2-bicyclo[2.2.1]heptanyl)oxy]phosphanyl]-N-ethylethanamine 以 氯仿 为溶剂， 以99%的产率得到N-[bis[(1,7,7-trimethyl-2-bicyclo[2.2.1]heptanyl)oxy]phosphanyl]-N-ethylethanamine;dichloropalladium
  参考文献：
  名称：

  Reactions of chiral phosphoramidites with complexes Pd(COD)Cl2 and Pt(COD)Cl2

  摘要：

  Reactions of phosphoramidites based on (-)-ephedrine and [(1S)-endo]-(-)-borneol with the complexes M(COD)Cl-2 (M is Pd or Pt, and COD is cycloocta-1,5-diene) were studied. The formation of cis and trans complexes of the general formulas MCl2L2 and M2Cl2(mu-Cl)(2)-L-2 was observed. The structures of the resulting compounds were established by P-31, C-13, and Pt-195 NMR and IR spectroscopy and by plasma desorption mass spectrometry.

  DOI：

  10.1007/bf02495615