[Ag2(8-[(pyridin-3-yl)methylthio]quinoline)2(CF3CO2)2] | 1121976-94-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [Ag2(8-[(pyridin-3-yl)methylthio]quinoline)2(CF3CO2)2]
• CAS: 1121976-94-0
• 化学式: C₃₄H₂₄Ag₂F₆N₄O₄S₂
• 分子量: 946.448
• InChiKey: RFIPCTIAUNQSEQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  8-((pyridin-3-yl)methylthio) quinoline 、 silver trifluoroacetate 以 氯仿 、 丙酮 、 乙腈 为溶剂， 以70%的产率得到[Ag2(8-[(pyridin-3-yl)methylthio]quinoline)2(CF3CO2)2]
  参考文献：
  名称：

  Syntheses, structures and bioactivities of silver(I) complexes with a tridentate heterocyclic N- and S-ligand

  摘要：

  Three silver(I) complexes of the asymmetric tridentate ligand 8-((pyridin-3-yl)methylthio)quinoline (TQMP3), namely [Ag-2(TQMP3)(2)(NO3)(2)] (1), [Ag-2(TQMP3)(2)(CF3CO2)(2)] (2) and {[Ag-2(TQMP3)(2)](CF3SO3)(2) (H2O)}(n) (3), have been prepared by the method of layering and diffusing of diethyl ether. The structures of the complexes have been identified by elemental analysis (EA), infrared spectra (IR) and single-crystal diffraction, and are composed of discrete binuclear rings in complexes 1 and 2, with pi-pi interactions or H-bonds further extending the structures into 2D nets, while in complex 3, Ag center dot center dot center dot Ag interactions between the rings result in a 1D polymer chain. The antibacterial, antifungal and pesticide activities of the three complexes were tested. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.09.029