3,3',3''-((1,3,5-triazine-2,4,6-triyl)tris(azanediyl))tribenzoic acid | 1383425-68-0

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物 - 环羧酸
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3',3''-((1,3,5-triazine-2,4,6-triyl)tris(azanediyl))tribenzoic acid
• 英文别名: 4,4′,4''-s-triazine-1,3,5-triyltri-m-aminobenzoate；4,4',4''-s-triazine-1,3,5-triyltri-m-aminobenzoic acid；4,4,4"-s-triazine-1,3,5-triyltri-m-aminobenzoic acid；4,4',4''-s-triazine-1,3,5-triyltri-m-aminobenzoate；H₃TATAB；3-[[4,6-bis(3-carboxyanilino)-1,3,5-triazin-2-yl]amino]benzoic acid
• CAS: 1383425-68-0
• 化学式: C₂₄H₁₈N₆O₆
• 分子量: 486.444
• InChiKey: PTYGUPSTBTUWKH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  36
• 可旋转键数：
  9
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  187
• 氢给体数：
  6
• 氢受体数：
  12

安全信息

• 危险性防范说明：
  P261,P280,P301+P312,P302+P352,P305+P351+P338
• 危险性描述：
  H302,H315,H319,H335

反应信息

• 作为反应物：
  描述：

  europium(III) nitrate hexahydrate 、 3,3',3''-((1,3,5-triazine-2,4,6-triyl)tris(azanediyl))tribenzoic acid 在 sodium hydroxide 作用下， 以 水 为溶剂， 反应 24.25h， 以67%的产率得到
  参考文献：
  名称：

  具有丰富路易斯碱位点的新型 3D MOF 作为 knoevenagel 缩合反应的碱催化

  摘要：

  摘要 采用半刚性有机配体 4,4,4″-s-triazine-1，溶剂热合成了一种具有高稳定性的新型 3D MOF，{[Eu(TATMA)(H2O)·2H2O}n（即 1）， 3,5-triyltri-m-aminobenzoic acid（表示为 H3TATMA）和 Eu(III) 离子。高稳定性主要归功于 1D Eu(III) 链作为无机节点。 此外，1 已通过单晶 X 射线衍射、粉末 X 射线衍射、元素分析（C、H 和 N）进行了详细表征和热重分析。由于其大量的路易斯碱性位点和1中的高稳定性，它可以被认为是Knoevenagel缩合反应的一种优异的多相碱催化。此外，回收样品可以重复使用至少四次而不会损失任何活性。

  DOI：

  10.1016/j.molstruc.2018.04.078
• 作为产物：
  描述：

  三聚氯氰 、 间氨基苯甲酸 在 sodium hydroxide 作用下， 以 水 为溶剂， 反应 12.0h， 以85%的产率得到3,3',3''-((1,3,5-triazine-2,4,6-triyl)tris(azanediyl))tribenzoic acid
  参考文献：
  名称：

  Microwave-assisted SNAr reaction of 2,4,6-trichloro-1,3,5-triazine for the rapid synthesis of C3-symmetrical polycarboxylate ligands

  摘要：

  The microwave-assisted SNAr reaction of 2,4,6-trichloro-1,3,5-triazine with various unprotected amino acids was developed for the synthesis of C-3-symmetrical polycarboxylate ligands which can be used as structural directing units in metal-organic frameworks. The reactions were performed in water using a domestic microwave oven as the heating device. In comparison to the reactions performed under conventional heating, the reactions under microwave irradiation proceeded much more rapidly within 20 min to afford the desired ligands in comparative yields to those obtained by conventional heating. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.04.124

文献信息

• Metal–organic framework composites with luminescent gold(<scp>iii</scp>) complexes. Strongly emissive and long-lived excited states in open air and photo-catalysis
  作者：Chun-Yi Sun、Wai-Pong To、Xin-Long Wang、Kaai-Tung Chan、Zhong-Min Su、Chi-Ming Che

  DOI：10.1039/c5sc02216a

  日期：——

  Encapsulation of luminescent gold(iii) complexes by metal–organic frameworks results in enhanced phosphorescence in open air, solid state two-photon-induced phosphorescence, and reusable photo-catalysts under aerobic conditions.

  金（III）荧光配合物的包埋在金属有机框架中，可以在空气中增强磷光，固态双光子诱导磷光，并在氧气条件下可重复使用的光催化剂。
• A luminescent metal–organic framework as an ideal chemosensor for nitroaromatic compounds
  作者：Hongming He、Si-Hang Chen、De-Yu Zhang、En-Cui Yang、Xiao-Jun Zhao

  DOI：10.1039/c7ra06320b

  日期：——

  A luminescent two-dimensional metal–organic framework, [(Pr2(TATMA)2)·4DMF·4H2O]n (1), was solvothermally synthesized based on the semi-rigid organic ligand 4,4′,4′′-s-triazine-1,3,5-triyltri-m-aminobenzoate (H3TATMA). 1 possesses binuclear Pr2(COO)6} subunits and fully deprotonated TATMA3− organic ligands, which can be further simplified into a 3,6-connected kgd topology with the Schläfli symbol

  基于半刚性有机配体4,4'，4''溶剂热合成了发光的二维金属有机骨架[[Pr 2（TATMA）2）·4DMF·4H 2 O] n（1）。 -小号嗪-1,3,5- triyltri-米-氨基苯甲酸（H 3 TATMA）。1具有双核Pr 2（COO）6 }亚基和完全去质子化的TATMA 3-有机配体，可以进一步简化为3,6-连接的kgd拓扑，其Schläfli符号为（4 3）2（4 6 ·6）6·8 3）。更重要的是，1通过发光响应显示出对硝基芳香族化合物（尤其是TNP）快速且可逆的固态检测。
• A Water‐Stable Terbium(III)–Organic Framework as a Chemosensor for Inorganic Ions, Nitro‐Containing Compounds and Antibiotics in Aqueous Solutions
  作者：Jun‐Hua Wei、Jing‐Wei Yi、Min‐Le Han、Bo Li、Shan Liu、Ya‐Pan Wu、Lu‐Fang Ma、Dong‐Sheng Li

  DOI：10.1002/asia.201900706

  日期：2019.10.15

  detecting Fe3+ , MnO4 - , 4-nirophenol and nitroimidazole (ronidazole, metronidazole, dimetridazole, ornidazole) in aqueous through luminescent quenching. The results suggest that Tb-MOF is a simple and reliable reagent with multiple sensor responses in practical applications. To the best of our knowledge, this work represents the first TbIII -based MOF as an efficient fluorescent sensor for detecting metal

  有效检测有机/无机污染物，例如抗生素，硝基化合物，过量的Fe3 +和MnO4-对人类健康和环境保护至关重要。在这里，一个新的ter（III）-有机骨架，即[Tb（TATAB）（H2 O）]⋅2H2O（Tb-MOF，H3 TATAB = 4,4'，4''-s-triazine-1,3组装并表征（5-5-三基三-间氨基苯甲酸）。Tb-MOF展示了水稳定的3D bnn框架。由于存在竞争性吸收，Tb-MOF具有高选择性，可通过发光猝灭检测水溶液中的Fe3 +， --，4-硝基苯酚和硝基咪唑（ronidazole，甲硝唑，dimetridazole，ornidazole）。结果表明，Tb-MOF是一种简单可靠的试剂，在实际应用中具有多个传感器响应。据我们所知，
• An Ultrastable Europium(III)–Organic Framework with the Capacity of Discriminating Fe²⁺/Fe³⁺ Ions in Various Solutions
  作者：Guo-Xuan Wen、Ya-Pan Wu、Wen-Wen Dong、Jun Zhao、Dong-Sheng Li、Jian Zhang

  DOI：10.1021/acs.inorgchem.6b01876

  日期：2016.10.17

  An ultrastable luminescent europium-organic framework, [Eu (L) (H2O)(2)]center dot NMP center dot H2O}(n) (CTGU-2; NMP = N-methyl-2-pyrrolidone), can first detect Fe2+/Fe3+ cations in different medium systems with high selectivity and sensitivity, and it also exhibits high sensitivity for Cr2O72- anion and acetone with a wide linear range and a low detection limit.
• An Exceptionally Stable Tb^III-Based Metal–Organic Framework for Selectively and Sensitively Detecting Antibiotics in Aqueous Solution
  作者：Qian-Qian Zhu、Hongming He、Ying Yan、Jing Yuan、Di-Qiu Lu、De-Yu Zhang、Fuxing Sun、Guangshan Zhu

  DOI：10.1021/acs.inorgchem.9b00147

  日期：2019.6.17

  An exceptionally stable metal-organic framework based on one-dimensional (1D) Tb-III chains with significant green emission under excitation energy, [Tb-(TATMA)(H2O)center dot 2H(2)O}(n) (namely, 1), has been fabricated successfully under hydrothermal conditions. By virtue of the spectral overlap between the absorbance spectra of nitrofurans (NFAs) and the excitation spectrum of MOF 1, the resultant sample exhibits outstandingly sensitive and selective luminescence detectability for NFT (K-sv = 3.35 x 10(4) M-1) and NFZ (K-sv = 3.00 X 10(4) M-1) by quenching phenomenon. More importantly, it can detect NFAs in water from bovine serum samples. The portable MOF film can be easily prepared and used with excellent stability and recursitivity.