[Ni(N,N'-bis(quinoline-2-carboxamido)-4-methylbenzene(-2H))] | 1240120-69-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [Ni(N,N'-bis(quinoline-2-carboxamido)-4-methylbenzene(-2H))]
• 英文别名: [Ni(Mebqb)]
• CAS: 1240120-69-7
• 化学式: C₂₇H₁₈N₄NiO₂
• 分子量: 489.156
• InChiKey: BCNRHTAGUIBPFU-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  N,N'-bis(quinoline-2-carboxamido)-4-methylbenzene 、 nickel(II) acetate tetrahydrate 以 乙醇 、 丙酮 为溶剂， 以88%的产率得到[Ni(N,N'-bis(quinoline-2-carboxamido)-4-methylbenzene(-2H))]
  参考文献：
  名称：

  Structural effects on electrochemical properties of the carboxamide complexes [NiII(Mebpb)] and [NiII(Mebqb)]

  摘要：

  Two Ni(II) complexes of the dianionic ligands, Mebpb(2-) , [H(2)Mebpb = N,N'-bis(pyridine-2-carboxamido)-4- methylbenzene] and Mebqb(2-), [H(2)Mebqb = N,N'-bis(quinoline-2-carboxamido)-4-methylbenzene] have been synthesized and characterized by elemental analyses, IR, and UV-Vis spectroscopy. The crystal and molecular structures of [Ni(Mebpb)], (1), and [Ni(Mebqb)], (2), were determined by X-ray crystallography. Both complexes exhibit distorted square-planar NiN4 coordination figures with two short and two long Ni-N bonds (Ni-N similar to 1.84 and similar to 1.95 angstrom, respectively). The electrochemical behavior of these complexes with the goal of evaluating the structural effects on the redox properties has been studied. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.05.020