[germanium(IV)(bis(2,6-diphenylphenoxy)(methyl)(iodide)] | 1262898-06-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [germanium(IV)(bis(2,6-diphenylphenoxy)(methyl)(iodide)]
• CAS: 1262898-06-5
• 化学式: C₃₇H₂₉GeIO₂
• 分子量: 705.131
• InChiKey: DLOCJCQQFYDJNX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  2,6-二苯基苯酚 、 [germanium(IV)(bis(2,6-diphenylphenoxy)(methyl)(iodide)] 、 苯 以 苯 为溶剂， 以77%的产率得到[germanium(IV)(2,6-diphenylphenoxy)3(methyl)] benzene monosolvate
  参考文献：
  名称：

  Synthesis and structures of aryloxo- and binaphthoxogermanium(IV) alkyl iodide complexes

  摘要：

  The germanium(II) aryloxide complexes (S)-[Ge{O2C20H10-(SiMe2Ph)(2)-3,3'}{NH3}] (1) and [Ge(OC6H3Ph2-2,6)(2)] (2) react with either (BuI)-I-t or MeI to yield the corresponding germanium(IV) compounds (S)-[Ge{O2C20H10-(SiMe2Ph)(2)-3,3'}{Bu-t}{I}] (3), (S)-[Ge{O2C20H10-(SiMe2Ph)(2)-3,3'}{Me}{I}] (4), [Ge(OC6H3Ph2-2,6)(2)(Bu-t)(I)] (5), and [Ge(OC6H3Ph2-2,6)(2)(Me)(I)] (6). Compound 6 reacts with 2,6-diphenylphenol to yield [Ge(OC6H3Ph2-2,6)(3)(Me)] (7), while 3-5 do not. The X-ray crystal structures of 3-5 and 7 were determined, and 3-5 represent the first structurally characterized germanium(IV) species having germanium bound to both oxygen and iodine. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.06.060
• 作为产物：
  描述：

  bis(2,6-diphenylphenoxide)germanium(II) 、 碘甲烷 以 苯 为溶剂， 以86%的产率得到[germanium(IV)(bis(2,6-diphenylphenoxy)(methyl)(iodide)]
  参考文献：
  名称：

  Synthesis and structures of aryloxo- and binaphthoxogermanium(IV) alkyl iodide complexes

  摘要：

  The germanium(II) aryloxide complexes (S)-[Ge{O2C20H10-(SiMe2Ph)(2)-3,3'}{NH3}] (1) and [Ge(OC6H3Ph2-2,6)(2)] (2) react with either (BuI)-I-t or MeI to yield the corresponding germanium(IV) compounds (S)-[Ge{O2C20H10-(SiMe2Ph)(2)-3,3'}{Bu-t}{I}] (3), (S)-[Ge{O2C20H10-(SiMe2Ph)(2)-3,3'}{Me}{I}] (4), [Ge(OC6H3Ph2-2,6)(2)(Bu-t)(I)] (5), and [Ge(OC6H3Ph2-2,6)(2)(Me)(I)] (6). Compound 6 reacts with 2,6-diphenylphenol to yield [Ge(OC6H3Ph2-2,6)(3)(Me)] (7), while 3-5 do not. The X-ray crystal structures of 3-5 and 7 were determined, and 3-5 represent the first structurally characterized germanium(IV) species having germanium bound to both oxygen and iodine. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.06.060