[Pd(μ-(N-(2-mercaptoethyl)-3,5-dimethylpyrazole(1-)))(1,3-bis(diphenylphosphino)propane)][BF4] | 676259-46-4

• 英文名称: [Pd(μ-(N-(2-mercaptoethyl)-3,5-dimethylpyrazole(1-)))(1,3-bis(diphenylphosphino)propane)][BF4]
• 英文别名: [Pd(μ-(N-(2-mercaptoethyl)-3,5-dimethylpyrazole(1-)))dppp][BF4]
• CAS: 676259-46-4
• 化学式: BF₄*C₃₄H₃₇N₂P₂PdS
• 分子量: 760.919
• InChiKey: DXHMNJOWQAFVAL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  双(乙腈)氯化钯(II) 、 [Pd(μ-(N-(2-mercaptoethyl)-3,5-dimethylpyrazole(1-)))(1,3-bis(diphenylphosphino)propane)][BF4] 、 [Pd(μ-(N-(2-mercaptoethyl)-3,5-dimethylpyrazole(1-)))dppp]2[BF4]2 以 二氯甲烷 为溶剂， 以59%的产率得到[Pd(μ-Cl)dppp]2[BF4]2
  参考文献：
  名称：

  Reactivity of [PdCl(μ-med)]2 with monodentate or bidentate ligands. Structure of the dinuclear complexes [Pd(μ-med)(PPh3)]2(BF4)2 and [Pd(μ-med)(bpy)]2(BF4)2. [Hmed=N-(2-mercaptoethyl)-3,5-dimethylpyrazole]

  摘要：

  Treatment of the ligand N-(2-mercaptoethyl)-3,5-dimethylpyrazole with [Pd(CH3COO)(2)](3) and reaction of [PdCl(mu-med)](2) with pyridine (py) or triphenylphosphine (PPh3) in the presence of AgBF4 produced the following complexes: [Pd(CH3COO)(mu-med)](2), [Pd(mu-med)(py)](2)(BF4)(2) and [Pd(mu-med)(PPh3)](2)(BF4)(2). Similar reactions carried out with 2,2'-bipyridine (bpy) or 1,3-bis(diphenylphosphino)propane (dppp) produced [Pd(mu-med)(bpy)](x)(BF4)(x) (x = 1 or 2) and [Pd(mu-med)(dppp)](x)(BF4)(x) (x = 1 or 2). Treatment of [Pd(mu-med)(bpy)](x)(BF4)(x) with [PdCl2(CH3CN)(2)] produced [Pd3Cl2(mu-med)(2)(bpy)(2)](BF4)(2). Treatment of [Pd (mu-med)(dppp)](x)(BF4)(x) with [PdCl2(CH3CN)(2)] produced a mixture of [Pd(mu-Cl)(dppp)](2)(BF4)(2) and [Pd(mu-med)(2)(dppp)](2+). X-ray crystal structures of [Pd(mu-med)(PPh3)](2)(BF4)(2) . 2CH(3)CN and [Pd(mu-med)(bpy)](2)(BF4)(2) . 0.5CH(3)OH are presented. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.08.013
• 作为产物：
  描述：

  乙腈 、 1,3-双(二苯基膦)丙烷 、 [Pd(μ-(N-(2-mercaptoethyl)-3,5-dimethylpyrazole(1-)))Cl]2 、 silver tetrafluoroborate 以 甲醇 、 二氯甲烷 、 乙腈 为溶剂， 以83%的产率得到[Pd(μ-(N-(2-mercaptoethyl)-3,5-dimethylpyrazole(1-)))dppp]2[BF4]2
  参考文献：
  名称：

  Reactivity of [PdCl(μ-med)]2 with monodentate or bidentate ligands. Structure of the dinuclear complexes [Pd(μ-med)(PPh3)]2(BF4)2 and [Pd(μ-med)(bpy)]2(BF4)2. [Hmed=N-(2-mercaptoethyl)-3,5-dimethylpyrazole]

  摘要：

  Treatment of the ligand N-(2-mercaptoethyl)-3,5-dimethylpyrazole with [Pd(CH3COO)(2)](3) and reaction of [PdCl(mu-med)](2) with pyridine (py) or triphenylphosphine (PPh3) in the presence of AgBF4 produced the following complexes: [Pd(CH3COO)(mu-med)](2), [Pd(mu-med)(py)](2)(BF4)(2) and [Pd(mu-med)(PPh3)](2)(BF4)(2). Similar reactions carried out with 2,2'-bipyridine (bpy) or 1,3-bis(diphenylphosphino)propane (dppp) produced [Pd(mu-med)(bpy)](x)(BF4)(x) (x = 1 or 2) and [Pd(mu-med)(dppp)](x)(BF4)(x) (x = 1 or 2). Treatment of [Pd(mu-med)(bpy)](x)(BF4)(x) with [PdCl2(CH3CN)(2)] produced [Pd3Cl2(mu-med)(2)(bpy)(2)](BF4)(2). Treatment of [Pd (mu-med)(dppp)](x)(BF4)(x) with [PdCl2(CH3CN)(2)] produced a mixture of [Pd(mu-Cl)(dppp)](2)(BF4)(2) and [Pd(mu-med)(2)(dppp)](2+). X-ray crystal structures of [Pd(mu-med)(PPh3)](2)(BF4)(2) . 2CH(3)CN and [Pd(mu-med)(bpy)](2)(BF4)(2) . 0.5CH(3)OH are presented. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.08.013