6-azidohexyl 2,4,6-tri-O-acetyl-3-O-benzyl-α-D-mannopyranosyl-(1->3)-2,4,6-tri-O-acetyl-β-D-galactopyranoside | 936550-04-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 6-azidohexyl 2,4,6-tri-O-acetyl-3-O-benzyl-α-D-mannopyranosyl-(1->3)-2,4,6-tri-O-acetyl-β-D-galactopyranoside
• CAS: 936550-04-8
• 化学式: C₃₇H₅₁N₃O₁₇
• 分子量: 809.822
• InChiKey: AEAFEBSFHFGHNL-WCHSRAEDSA-N

反应信息

• 作为反应物：
  描述：

  6-azidohexyl 2,4,6-tri-O-acetyl-3-O-benzyl-α-D-mannopyranosyl-(1->3)-2,4,6-tri-O-acetyl-β-D-galactopyranoside 在 sodium bromate 、 sodium dithionite 作用下， 以 水 、 乙酸乙酯 为溶剂， 以80%的产率得到6-azidohexyl 2,4,6-tri-O-acetyl-α-D-mannopyranosyl-(1->3)-2,4,6-tri-O-acetyl-β-D-galactopyranoside
  参考文献：
  名称：

  Synthesis of a fluorescence-labeled K30 antigen repeating unit using click chemistry

  摘要：

  An N-dansyl-labeled K30 antigen repeating unit, {4-[5-(N,N'-dimethylamino)naphthalene-1-sulfonamine]-1H-1,2,3-triazol-1-yl}hexyl beta-D-glucopyranosyluronate-(1 -> 3)-alpha-D-galactopyranosyl-alpha-D-mannopyranosyl-(1 -> 3)-beta-D-galactopyranoside, was synthesized using click chemistry, the copper(I)-catalyzed 1,3-dipolar cycloaddition reaction of an azide and an alkyne. The target compound could further facilitate the studies of interactions among K30 oligosaccharides and proteins. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2007.01.015
• 作为产物：
  描述：

  6-azidohexyl 2,4,6-tri-O-acetyl-3-O-benzyl-α-D-mannopyranosyl-(1->3)-2-O-acetyl-4,6-O-benzylidene-β-D-galactopyranoside 、 乙酸酐 在 水 、 溶剂黄146 、 吡啶 作用下， 反应 6.0h， 以2.62 g的产率得到6-azidohexyl 2,4,6-tri-O-acetyl-3-O-benzyl-α-D-mannopyranosyl-(1->3)-2,4,6-tri-O-acetyl-β-D-galactopyranoside
  参考文献：
  名称：

  Synthesis of a fluorescence-labeled K30 antigen repeating unit using click chemistry

  摘要：

  An N-dansyl-labeled K30 antigen repeating unit, {4-[5-(N,N'-dimethylamino)naphthalene-1-sulfonamine]-1H-1,2,3-triazol-1-yl}hexyl beta-D-glucopyranosyluronate-(1 -> 3)-alpha-D-galactopyranosyl-alpha-D-mannopyranosyl-(1 -> 3)-beta-D-galactopyranoside, was synthesized using click chemistry, the copper(I)-catalyzed 1,3-dipolar cycloaddition reaction of an azide and an alkyne. The target compound could further facilitate the studies of interactions among K30 oligosaccharides and proteins. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2007.01.015