(13S)-ent-6α,18-diacetoxy-8(14-16)-14-deuteromanoyl oxide | 134952-99-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (13S)-ent-6α,18-diacetoxy-8(14-16)-14-deuteromanoyl oxide
• CAS: 134952-99-1
• 化学式: C₂₄H₃₈O₅
• 分子量: 407.555
• InChiKey: ZZODVWZKJDRUSS-SBKBKRIQSA-N

反应信息

• 作为产物：
  描述：

  6,18-diacetyl andalusol 生成 (13S)-ent-6α,18-diacetoxy-8(14-16)-14-deuteromanoyl oxide
  参考文献：
  名称：

  Intramolecular Addition of Hydroxy Group to a Diene System: Oxymercuration - Demercuration and Titanium Tetrachloride Catalyzed Synthesis of Manoyl Oxides

  摘要：

  The stereochemistry of the formation of tetrahydropyran ring of ent-manoyl oxides from ent-8α-hydroxylabda-13(16), 14-dienes has been studied in one and two-step oxymercuration-demercuration (OM-DM) processes as well as by a new titanium tetrachloride catalyzed cyclization which allows the preparation of this tetrahydropyran moiety of C-13 epimer manoyl oxides in high yield.

  DOI：

  10.1055/s-1991-26468