六氢苯甲酸铜 | 533-01-7

• 物质功能分类: 有机原料 - 有机金属盐
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 六氢苯甲酸铜
• 中文别名: 六氫苯甲酸銅
• 英文名称: Benzoic acid;copper
• CAS: 533-01-7；14067-34-6
• 化学式: C7H6CuO2
• 分子量: 185.67
• InChiKey: WLLASMDMMUPSMP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.38
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

文献信息

• Method for production of halogen-containing phthalocyanine compound
  申请人：Hirota Kouichi

  公开号：US20050203293A1

  公开（公告）日：2005-09-15

  This invention relates to a method for for the production of a halogen-containing phthalocyaline compound by the cyclization of phthalonitrile compounds either singly or in combination with a metal compound, characterized in effecting the cyclization in an organic compound having a hydroxyl group and/or a carboxylic acid in an amount in the range of 0.01-10 mass parts per one mass part of the phthalonitrile compounds while continuing the introduction of an inert gas. This method, by using a solvent capable of serving as a specific oxygen source destined to participate in the reaction of complexing a metal compound introduced into a phthalocyanine dye, permits the production of a phthalocyanine compound inexpensively in a high yield.

  这项发明涉及一种通过在具有羟基和/或羧酸的有机化合物中以每一部分邻苯二腈化合物0.01-10质量部的量的情况下，通过将邻苯二腈化合物单独或与金属化合物组合进行环化来生产含卤素的酞菁化合物的方法，其特征在于在继续引入惰性气体的同时进行环化。通过使用能够作为特定氧源的溶剂来参与将引入到酞菁染料中的金属化合物络合反应的方法，可以以高产率廉价地生产酞菁化合物。
• [EN] PROCESS FOR PREPARING CHIRAL DIPEPTIDYL PEPTIDASE-IV INHIBITORS<br/>[FR] PROCÉDÉ DE PRÉPARATION D'INHIBITEURS CHIRAUX DE DIPEPTIDYL PEPTIDASE-IV
  申请人：MERCK SHARP & DOHME

  公开号：WO2016014324A1

  公开（公告）日：2016-01-28

  A process for preparing a compound of structural Formula Ia: comprising Boc deprotection with TFA of, reductive amination of:.

  制备结构式Ia化合物的过程：包括使用三氟乙酸对Boc进行去保护，还有还原胺化反应。
• ARYLOAZOL-2-YL CYANOETHYLAMINO COMPOUNDS, METHOD OF MAKING AND METHOD OF USING THEREOF
  申请人：Soll Mark David

  公开号：US20140080862A1

  公开（公告）日：2014-03-20

  The present invention relates to novel aryloazol-2-yl-cyanoethylamino derivatives of formula (I): wherein R 3 , R 4 , R 5 , R 6 , R 7 , P, Q, V, W, X, Y, Z and a are as defined in the description, compositions thereof, processes for their preparation and their uses as pesticides.

  本发明涉及新颖的式(I)的芳基咪唑-2-基-氰基乙基氨基衍生物：其中R3、R4、R5、R6、R7、P、Q、V、W、X、Y、Z和a如描述中所定义，以及其组合物、制备方法以及它们作为杀虫剂的用途。
• Preparation of 2,3,3',4' -biphenyltetracarboxylic acid tetraester
  申请人：Tsuji Tetsuro

  公开号：US20050090683A1

  公开（公告）日：2005-04-28

  2,3,3′,4′-Biphenyltetracarboxylic acid tetraester is predominantly produced by a process in which a phthalic acid diester is subjected to oxidative-coupling reaction in the presence of molecular oxygen and a catalyst comprising a rhodium-containing compound,.

  2,3,3′,4′-联苯四羧酸四酯主要是通过一种过程生产的，该过程中邻苯二甲酸二酯在分子氧和含铑化合物催化剂存在下进行氧化偶联反应。
• Process for production of biphenyltetracarboxylic acid tetraesters
  申请人：UBE INDUSTRIES, LTD.

  公开号：US20040039222A1

  公开（公告）日：2004-02-26

  A production process, especially a continuous production process, for a biphenyltetracarboxylic acid tetraester characterized by carrying out, in parallel, a step of preliminarily mixing a phthalic acid diester and a palladium compound-containing catalyst to prepare a starting mixture, a step of continuously or intermittently supplying the starting mixture to a reactor, a step of conducting oxidative dimerization reaction of the phthalic acid diester in a temperature range of from 140° C. and lower than 250° C. while supplying molecular oxygen to the reactor to form a reaction mixture in the reactor, and a step of continuously or intermittently removing a portion of the reaction mixture from the reactor. Preferably, the palladium compound-containing catalyst in the starting mixture is dissolved in the phthalic acid diester, the palladium compound-containing catalyst comprises a palladium compound, a bidentate ligand and a copper compound, the reactor consists of a plurality of serially connected reactors and a carboxylic acid is also continuously or intermittently supplied to the reactor.

  一种生产过程，特别是用于制备二苯四羧酸四酯的连续生产过程，其特征在于并行进行以下步骤：预先混合邻苯二甲酸二酯和含钯化合物催化剂以制备起始混合物的步骤；连续或间歇地将起始混合物供给反应器的步骤；在向反应器供给分子氧以在温度范围从140°C至低于250°C内进行邻苯二甲酸二酯的氧化二聚反应以在反应器中形成反应混合物的步骤；以及连续或间歇地从反应器中移除部分反应混合物的步骤。优选，起始混合物中的含钯化合物催化剂溶解在邻苯二甲酸二酯中，含钯化合物催化剂包括钯化合物、双齿配体和铜化合物，反应器由多个串联的反应器组成，并且还连续或间歇地向反应器供给羧酸。