ethyl 3-ethoxy-3-((2S,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran-2-yloxy)acrylate | 1193390-76-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: ethyl 3-ethoxy-3-((2S,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran-2-yloxy)acrylate
• CAS: 1193390-76-9
• 化学式: C₄₁H₄₆O₉
• 分子量: 682.811
• InChiKey: ICJJRZIVVWJLIH-VPTYZSTFSA-N

反应信息

• 作为产物：
  描述：

  2,3,4,6-四-o-苄基-D-吡喃葡萄糖 、 丙二酸二乙酯 在 三丁基膦 、 偶氮二甲酰胺 作用下， 以 苯 为溶剂， 以35%的产率得到ethyl 3-ethoxy-3-((2S,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran-2-yloxy)acrylate
  参考文献：
  名称：

  A Mitsunobu route to C-glycosides

  摘要：

  C-Glycosides were successfully prepared via dehydrative alkylation under Mitsunobu conditions, using substituted sulfonyl methanes as nucleophiles. The materials prepared were converted to useful C-glycoside intermediates. An application of this approach toward the synthesis of C-glycolipids is presented. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.08.024