(2E,6E,10E)-(4R,14S)-14-Hydroxy-2,6,10,14-tetramethyl-4-((S)-3,3,3-trifluoro-2-methoxy-2-phenyl-propionyloxy)-hexadeca-2,6,10,15-tetraenoic acid | 144125-20-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (2E,6E,10E)-(4R,14S)-14-Hydroxy-2,6,10,14-tetramethyl-4-((S)-3,3,3-trifluoro-2-methoxy-2-phenyl-propionyloxy)-hexadeca-2,6,10,15-tetraenoic acid
• CAS: 144125-20-2
• 化学式: C₃₀H₃₉F₃O₆
• 分子量: 552.631
• InChiKey: IFLFVGZQSPZWOM-LDKTZJMOSA-N

反应信息

• 作为产物：
  描述：

  (R)-methoxytrifluoromethylphenylacetyl chloride 、 (2E,6E,10E)-(4R,14S)-4,14-Dihydroxy-2,6,10,14-tetramethyl-hexadeca-2,6,10,15-tetraenoic acid 在 吡啶 作用下， 以10 mg的产率得到(2E,6E,10E)-(4R,14S)-14-Hydroxy-2,6,10,14-tetramethyl-4-((S)-3,3,3-trifluoro-2-methoxy-2-phenyl-propionyloxy)-hexadeca-2,6,10,15-tetraenoic acid
  参考文献：
  名称：

  Studies on the Solanaceous Plants. Part XXIII. New Acyclic Diterpene Glycosides, Capsianosides VI, G and H from the Leaves and Stems of Capsicum annuum L.

  摘要：

  Capsicum species are very important plants used as vegetable foods, species and external medicines. In the preceding paper, we disclosed the occurrence of novel acylic diterpene glycosides from fruits of the Capsicum species. We now obtained three new acyclic diterpene glycosides, names capsianosides VI (1), G (2) and H (3), along with capsianosides II, A, B, C and D from the leaves and steam of the Capsicum annuum species, and their structures were elucidated by spectroscopic and chemical means.

  DOI：

  10.1248/cpb.39.3258