Phenyl-o-tolyliodonium | 64147-30-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: Phenyl-o-tolyliodonium
• 英文别名: o-Tolylphenyliodonium；(2-Methylphenyl)-phenyliodanium
• CAS: 64147-30-4
• 化学式: C₁₃H₁₂I
• 分子量: 295.143
• InChiKey: YTNCCAOJFLSGPW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• Method for preparing diaryl iodonium salts
  申请人：NIPPON PETROCHEMICALS COMPANY, LIMITED

  公开号：EP0119068A1

  公开（公告）日：1984-09-19

  A method for preparing diaryl iodonium salts represented by the formula: wherein Ar, and Ar2 may be the same or different and each is an aryl group which may be substituted with an electron donor group, the method comprising subjecting a compound represented by the formula Ar1-H wherein Ar1 is as defined above and a compound Ar2-1 wherein Ar2 is as defined above to a coupling reaction in a sulfuric acid solution containing an oxidizing agent and diluted with a diluting agent to a concentration of 85% by weight or less at a reaction temperature in the range from -20 to +35°C.

  一种制备由式表示的二芳基碘鎓盐的方法： 其中 Ar 和 Ar2 可以相同或不同，且各自为可被电子供体基团取代的芳基，该方法包括使式 Ar1-H 所代表的化合物（其中 Ar1 如上文所定义）和化合物 Ar2-1（其中 Ar2 如上文所定义）在含有氧化剂的硫酸溶液中进行偶联反应，该硫酸溶液用稀释剂稀释至浓度为 85%（重量）或更低，反应温度为-20 至 +35°C。
• High speed aqueous solvent developable photopolymer compositions
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0500321A1

  公开（公告）日：1992-08-26

  Novel photosensitive compositions based on azlactone derived polymers are described. The polymers have a hydrocarbyl backbone and pendant peptide groups with free-radically polymerizable functionality attached thereto, said polymer further comprising at least one oxyacid group or salt thereof, and optionally quaternary ammonium salt groups. A high speed durable printing plate having a mild pH aqueous developability is disclosed which incorporates these polymers in combination with a photoinitiator. The polymers are also useful as proofing films in graphic arts applications.

  本文描述了基于氮内酯衍生聚合物的新型光敏组合物。这些聚合物具有烃基骨架和附有可自由基聚合官能团的悬垂肽基，所述聚合物还包括至少一个氧酸基团或其盐，以及可选的季铵盐基团。本发明公开了一种具有温和 pH 值水性显影能力的高速耐久印版，它将这些聚合物与光引发剂结合在一起。这些聚合物还可用作图形艺术应用中的打样薄膜。
• Reactive polymeric dyes
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0621322A1

  公开（公告）日：1994-10-26

  Reactive polymeric dyes are provided comprising a chromophoric moiety derived from at least one free radically polymerizable dye and an azlactone moiety derived from 2-alkenylazlactone such that the free radically polymerizable dye is incorporated into the backbone of the polymer. Alternatively, 2-alkenylazlactone is polymerized and then derivatized with a nucleophilic dye or dyes, such that the chromophoric portion of the dye is pendent to the polymer backbone. Both types of reactive polymeric dyes may also contain additional polymerized monomeric units. The reactive polymeric dyes of the present invention can be used in a photoresist system and in particular in a color proofing construction.

  反应性聚合染料包括由至少一种可自由基聚合的染料衍生的发色分子和由 2-烯丙基氮内酯衍生的氮内酯分子，这样可自由基聚合的染料就与聚合物的骨架结合在一起。另一种方法是将 2-烯丙基氮杂环内酯聚合，然后用一种或多种亲核染料进行衍生，使染料的发色部分悬挂在聚合物骨架上。这两类活性聚合染料还可能含有额外的聚合单体单元。本发明的活性聚合染料可用于光致抗蚀剂系统，特别是用于彩色打样结构。
• Aminoketone sensitizers for aqueous soluble photopolymer compositions
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0538997B1

  公开（公告）日：1998-07-01
• Shoot and run printing materials
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0600615B1

  公开（公告）日：1997-01-22