3-(11-hydroxy-3,6,9-trioxa-1-undecoxy)thiophene | 171085-47-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-(11-hydroxy-3,6,9-trioxa-1-undecoxy)thiophene
• 英文别名: 2-[2-[2-(2-Thiophen-3-yloxyethoxy)ethoxy]ethoxy]ethanol
• CAS: 171085-47-5
• 化学式: C₁₂H₂₀O₅S
• 分子量: 276.354
• InChiKey: SFUINAYHPFUTIJ-UHFFFAOYSA-N

物化性质

• 沸点：
  398.2±37.0 °C(Predicted)
• 密度：
  1.175±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  18
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  85.4
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  3-(11-hydroxy-3,6,9-trioxa-1-undecoxy)thiophene 在 吡啶 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 、 丙酮 为溶剂， 生成 1,4-bis(2-(2-(2-(2-(thiophen-3-yloxy)ethoxy)ethoxy)ethoxy)ethoxy)benzene
  参考文献：
  名称：

  传导伪聚轮烷：通过分子识别的化学抵抗反应

  摘要：

  假轮烷是由环状分子组成的主客体系统，其空腔被相容的线性分子穿透。在准聚轮烷中，聚合物链可以充当环状主体或线性客体。在这两种情况下，准聚轮烷与其母体聚合物的物理性质显着不同。在自组装 ?r-供体/7r-受体系统的情况下，这种络合的驱动力是电荷转移相互作用。聚轮烷和拟聚轮烷的报道较多，但尚未对由导电性高分子衍生的拟聚轮烷进行研究。导电 Tolymers 表现出高度敏感的电阻率，并且会因环境影响而变化多个数量级。2 这种敏感性允许设计基于导电聚合物的传感材料，其中电阻率和/或氧化还原电位可以作为主客体相互作用产生的刺激的函数而变化。在此，我们报告了一种新型的基于聚噻吩的导电拟聚轮烷，它在存在 7r 缺陷的 4,4'-联吡啶客体的情况下表现出电导率的可逆衰减和氧化还原电位的阳极转移。我们对导电拟聚轮烷的设计部分基于 Stoddart 的证明，即双（对亚苯基）-34-冠 10 (BPP) 与缺乏βr

  DOI：

  10.1021/ja00099a069
• 作为产物：
  描述：

  3-溴噻吩 、 三缩四乙二醇 在 吡啶 、 copper(l) iodide 、 potassium tert-butylate 作用下， 以69%的产率得到3-(11-hydroxy-3,6,9-trioxa-1-undecoxy)thiophene
  参考文献：
  名称：

  传导伪聚轮烷：通过分子识别的化学抵抗反应

  摘要：

  假轮烷是由环状分子组成的主客体系统，其空腔被相容的线性分子穿透。在准聚轮烷中，聚合物链可以充当环状主体或线性客体。在这两种情况下，准聚轮烷与其母体聚合物的物理性质显着不同。在自组装 ?r-供体/7r-受体系统的情况下，这种络合的驱动力是电荷转移相互作用。聚轮烷和拟聚轮烷的报道较多，但尚未对由导电性高分子衍生的拟聚轮烷进行研究。导电 Tolymers 表现出高度敏感的电阻率，并且会因环境影响而变化多个数量级。2 这种敏感性允许设计基于导电聚合物的传感材料，其中电阻率和/或氧化还原电位可以作为主客体相互作用产生的刺激的函数而变化。在此，我们报告了一种新型的基于聚噻吩的导电拟聚轮烷，它在存在 7r 缺陷的 4,4'-联吡啶客体的情况下表现出电导率的可逆衰减和氧化还原电位的阳极转移。我们对导电拟聚轮烷的设计部分基于 Stoddart 的证明，即双（对亚苯基）-34-冠 10 (BPP) 与缺乏βr

  DOI：

  10.1021/ja00099a069

文献信息

• [EN] POLYMERS WITH BODIPY-BASED BACKBONE FOR SOLAR CELLS<br/>[FR] POLYMÈRES AVEC SQUELETTE À BASE DE BODIPY POUR DES CELLULES SOLAIRES
  申请人：UNIV MICHIGAN TECH

  公开号：WO2010075512A1

  公开（公告）日：2010-07-01

  The present application discloses the preparation of BODIPY-based backbone polymers for use in solar cell devices. Embodiments provide efficient solution-processed bulk heterojunction ("BHJ") polymer/PCBM solar cells with BODIPY-based backbone polymers (pBodipy and pBodipy-T) as the polymer electron donor. In some embodiments of the present application, solar cells exhibit highly efficient light harvesting of the solar spectrum up to ~1.6eV. CV data suggest these BODIPY-based backbone polymers have an optimal energy level alignment for charge separation in contact with PCBM, and deep HOMO levels that result in the high Voc of 0.8 V and efficiency of about 2%.

  本申请公开了用于太阳能电池器件的BODIPY基骨架聚合物的制备。实施例提供了高效的溶液加工的大体异质结（"BHJ"）聚合物/PCBM太阳能电池，其中BODIPY基骨架聚合物（pBodipy和pBodipy-T）作为聚合物电子给体。在本申请的一些实施例中，太阳能电池展现出对太阳光谱高效的光吸收，达到约1.6eV。CV数据表明，这些基于BODIPY的骨架聚合物与PCBM接触时具有最佳的能级对齐，有深的HOMO能级，导致高达0.8V的高Voc和约2%的效率。
• Design of chemoresistive sensory materials: polythiophene-based pseudopolyrotaxanes
  作者：Michael J. Marsella、Patrick J. Carroll、Timothy M. Swager

  DOI：10.1021/ja00144a008

  日期：1995.10

  Herein we report conducting polymer-based sensors which transduce reversible, noncovalent, and nonredox-dependent molecular recognition events into measurable changes in conductivity. These chemoresistive polymers are derived from bithiophenes containing cyclophane receptors capable of forming self-assembled pseudorotaxane complexes with paraquat. The electrostatic perturbations arising from pseudopolyrotaxane formation cause a decrease in carrier mobility and thus lower the conductivity. The chemoresistive response was found to be consistent with decreased carrier mobility and exhibited an enhanced sensitivity to analyte-promoted electrostatic perturbations relative to the voltammetric response. Polymer-based devices which demonstrate a real time chemoresistive response to paraquat are also reported.
• ENZYMATIC BIOSENSORS, HYDROGEL COMPOSITIONS THEREFOR, AND METHODS FOR THEIR PRODUCTION
  申请人：HITACHI CHEMICAL COMPANY AMERICA, LTD.

  公开号：US20190233869A1

  公开（公告）日：2019-08-01

  A biosensor ( 1 ) is disclosed that may include at least one electrode surface ( 3 ); a reagent layer ( 5 ) disposed on top of the at least one electrode surface ( 3 ) and a reagent layer ( 5 ) formed thereon. The reagent layer ( 5 ) is formed according to the principles of the present invention, and may include a redox enzyme, a redox polymer, and a cross-linked gel. The reagent layer ( 5 ) is structured to act as a conductive matrix that traps the redox polymer and enzyme at the electrode surface.
• [EN] REDOX MEDIATOR-FUNCTIONALIZED WATER-SOLUBLE POLYMER<br/>[FR] POLYMÈRE SOLUBLE DANS L'EAU FONCTIONNALISÉ PAR UN MÉDIATEUR REDOX
  申请人：HITACHI CHEMICAL CO AMERICA LTD

  公开号：WO2018039585A1

  公开（公告）日：2018-03-01

  Described herein are a series of water-soluble conjugated polymers having redox mediators and functional groups on flexible side chains. The polymers may include a backbone having a conjugated polymer; a first side chain attached to the backbone, the first side chain having a ferrocene group or a derivative thereof; a second side chain attached to the backbone, the second side chain having an organic acid, a salt of an organic acid, or quaternary ammonium; and at least one of the first and second side chains having at least one of a carbon atom, a nitrogen atom, an oxygen atom, and a sulfur atom. Because of their redox activity, water solubility and ease of further coupling with versatile functional species, the polymers discussed in this application can be used as sensor interface materials for various biosensor developments.
• [EN] ENZYMATIC BIOSENSORS, HYDROGEL COMPOSITIONS THEREFOR, AND METHODS FOR THEIR PRODUCTION<br/>[FR] BIO-CAPTEURS ENZYMATIQUES, COMPOSITIONS D'HYDROGEL POUR CEUX-CI ET LEURS PROCÉDÉS DE FABRICATION
  申请人：HITACHI CHEMICAL CO AMERICA LTD

  公开号：WO2018039572A1

  公开（公告）日：2018-03-01

  A biosensor (1) is disclosed that may include at least one electrode surface (3); a reagent layer (5) disposed on top of the at least one electrode surface (3) and a reagent layer (5) formed thereon. The reagent layer (5) is formed according to the principles of the present invention, and may include a redox enzyme, a redox polymer, and a cross- linked gel. The reagent layer (5) is structured to act as a conductive matrix that traps the redox polymer and enzyme at the electrode surface.