(E)-8,9-epoxyheptadecane | 93815-49-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 英文名称: (E)-8,9-epoxyheptadecane
• 英文别名: (Z)-8,9-epoxyheptadecane；2-heptyl-3-octyloxirane
• CAS: 93815-49-7
• 化学式: C₁₇H₃₄O
• 分子量: 254.456
• InChiKey: UWDZSCKMSGVFSQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  18
• 可旋转键数：
  13
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (E)-8,9-epoxyheptadecane 在 盐酸 作用下， 以 二氯甲烷 为溶剂， 反应 4.0h， 以90%的产率得到Heptadecan-8,9-diol
  参考文献：
  名称：

  用于从可再生脂肪酸合成脂肪环氧化物的光生物催化脱羧

  摘要：

  光生物催化：从可再生脂肪酸合成脂肪环氧化物是通过使用来自小球藻NC64A ( Cv FAP) 的光脱羧酶和四种同系物来实现的。这项工作扩展了新发现的光脱羧酶的已知底物特异性，用于合成化学中脂肪酸的价值化，提供了一种新的催化方法。

  DOI：

  10.1002/cssc.202201275
• 作为产物：
  描述：

  油酸 在 Chlorella variabilis NC₆₄A fatty acid photodecarboxylase 、 sodium carbonate 、 间氯过氧苯甲酸 作用下， 以 二氯甲烷 、 二甲基亚砜 为溶剂， 反应 8.0h， 生成 (E)-8,9-epoxyheptadecane
  参考文献：
  名称：

  用于从可再生脂肪酸合成脂肪环氧化物的光生物催化脱羧

  摘要：

  光生物催化：从可再生脂肪酸合成脂肪环氧化物是通过使用来自小球藻NC64A ( Cv FAP) 的光脱羧酶和四种同系物来实现的。这项工作扩展了新发现的光脱羧酶的已知底物特异性，用于合成化学中脂肪酸的价值化，提供了一种新的催化方法。

  DOI：

  10.1002/cssc.202201275

文献信息

• Reaction gas chromatography without solvent for identification of nanogram quantities of natural products
  作者：Athula B. Attygalle、E. David. Morgan

  DOI：10.1021/ac00259a043

  日期：1983.7.1
• BIO-BASED RESINS WITH HIGH CONTENT OF ETHYLENICALLY UNSATURATED FUNCTIONAL GROUPS AND THERMOSETS THEREOF
  申请人：NDSU RESEARCH FOUNDATION

  公开号：US20160280842A1

  公开（公告）日：2016-09-29

  The invention provides polyfunctional bio-based methacrylate oligomers, which are synthesized via the ring-opening reaction between at least one ethylenically unsaturated acid selected from methacrylic acid, acrylic acid, and crotonic acid, and a polyfunctional bio-based epoxy resin, such as epoxidized sucrose soyate. The extent of reaction may be varied to generate a family of methacrylate oligomers with differing degrees of methacrylate. These methacrylate oligomers can optionally be mixed with a reactive diluent, such as styrene, and cured using, for example, a thermally-activated free radical initiator to form a thermoset polymer with high modulus. The thermosets can be used to form composites, adhesives, coatings, and dental restorative materials. Methods of making the methacrylate oligomers are disclosed as are coating compositions and coated objects, such as dental restorative materials, using the methacrylate oligomers.
• [EN] BIO-BASED RESINS WITH HIGH CONTENT OF ETHYLENICALLY UNSATURATED FUNCTIONAL GROUPS AND THERMOSETS THEREOF<br/>[FR] RÉSINES D'ORIGINE BIOLOGIQUE PRÉSENTANT UNE TENEUR ÉLEVÉE EN GROUPES FONCTIONNELS ÉTHYLÉNIQUEMENT INSATURÉS, ET THERMODURCIS À BASE DE CELLES-CI
  申请人：NDSU RES FOUNDATION

  公开号：WO2015070018A1

  公开（公告）日：2015-05-14

  The invention provides poiyfunctionai bio-based methacrylate oligomers, which are synthesized via the ring-opening reaction between at least one ethyienicaliy unsaturated acid selected from methacrylic acid, acrylic acid, and crotonic acid, and a poiyfunctionai bio-based epoxy resin, such as epoxidized sucrose soyate. The extent of reaction may be varied to generate a family of methacrylate oligomers with differing degrees of methacryiation. These methacrylate oligomers can optionally be mixed with a reactive diluent, such as styrene, and cured using, for example, a thermally-activated free radical initiator to form a thermoset polymer with high modulus. The thermosets can be used to form composites, adhesives, coatings, and dental restorative materials. Methods of making the methacrylate oligomers are disclosed as are coating compositions and coated objects, such as dental restorative materials, using the methacrylate oligomers.
• Photobiocatalytic Decarboxylation for the Synthesis of Fatty Epoxides from Renewable Fatty Acids
  作者：Ran Ge、Pengpeng Zhang、Xuetian Dong、Yuanying Li、Zhoutong Sun、Yongyi Zeng、Bishuang Chen、Wuyuan Zhang

  DOI：10.1002/cssc.202201275

  日期：2022.10.21

  Photobiocatalysis: The synthesis of fatty epoxides from renewable fatty acids is achieved by using the photodecarboxylase from Chlorella variabilis NC64A (CvFAP) and four homologues. This work expands the known substrate specificity of the newly discovered photodecarboxylases for valorization of fatty acids in synthetic chemistry, offering a new catalytic methodology.

  光生物催化：从可再生脂肪酸合成脂肪环氧化物是通过使用来自小球藻NC64A ( Cv FAP) 的光脱羧酶和四种同系物来实现的。这项工作扩展了新发现的光脱羧酶的已知底物特异性，用于合成化学中脂肪酸的价值化，提供了一种新的催化方法。