| 154973-55-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 154973-55-4
• 化学式: C₂₀H₂₂N₃P₂ReS₂
• 分子量: 616.701
• InChiKey: ZFNQZNDTWQBVDE-NPDUFXBMSA-L

反应信息

• 作为产物：
  描述：

  、 disodium maleonitriledithiolato 以 甲醇 为溶剂， 以48%的产率得到
  参考文献：
  名称：

  Mixed-ligand complexes of rhenium III. Synthesis, characterisation and structures of [ReN(Me2PhP)2(mnt)] and [ReN(Me2PhP)(2,6-DMTP)(morphtcb)] (Me2PhP = dimethylphenylphosphine; 2,6-DMTP− = 2,6-dimethylthiophenolate; morphtcb−=N-(morpholinylthiocarbonyl)- benzamidinate)

  摘要：

  Novel rhenium(V) nitrido complexes have been prepared by ligand exchange procedures starting from [ReN(Cl)(Me2PbP)2(morphtcb)] and 2,6-dimethylthiophenol, 2,6-DMTPH, or sodium 1,2-dicyanoethene-1,2-dithiolate, Na2mnt. [ReN(Me2PhP)(2,6-DMTP)(morphtcb)] and [ReN(Me2Php)2(mnt)] are neutral, air-stable complexes which have been spectroscopically characterised and studied by X-ray diffraction. [ReN(Me2Php)2(mnt)] crystallises triclinic in the space group P1BAR (a = 9.802(3), b = 10.215(2), c = 12.389(3) angstrom, alpha = 69.38(2), e = 85.84(2), gamma = 78.84(6)-degrees) with Z = 2. The final R value is 0.021. The rhenium atom is five-coordinate with the nitrido nitrogen at the apex of a distorted square pyramid. [ReN(Me2PhP)(2,6-DMTP)(morphtcb)] crystallises monoclinic in the space group P2(1)/c (a = 11.609(2), b = 11.677(1), c = 21.923(6) angstrom, beta = 92.59(1)-degrees) with Z = 4. Structure solution and refinement based on 4626 reflections converged at R = 0.032. The coordination polyhedron is a square pyramid which is significantly distorted towards a trigonal bipyramid.

  DOI：

  10.1016/0020-1693(93)03729-t