Cu(II)(hexafluoroacetylacetonate)2(NC5H4NCHC6H3S4) | 940861-93-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: Cu(II)(hexafluoroacetylacetonate)2(NC5H4NCHC6H3S4)
• CAS: 940861-93-8
• 化学式: C₂₂H₁₀CuF₁₂N₂O₄S₄
• 分子量: 786.123
• InChiKey: TXTQYYIOBLNMCW-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  Cu(hexafluoroacetylacetonate)₂*2H₂O 、 1-[2-(1,3-dithiol-2-ylidene)-1,3-dithiol-4-yl]-N-pyridin-2-ylmethanimine 以 二氯甲烷 为溶剂， 以59%的产率得到Cu(II)(hexafluoroacetylacetonate)2(NC5H4NCHC6H3S4)
  参考文献：
  名称：

  Preparation and Coordination Complex of the First Imine-Bridged Tetrathiafulvalene−Pyridine Donor Ligand

  摘要：

  The first imine-bridged pyridyltetrathiafulvalene building block (TTF-CH=N-Py, 1) has been synthesized via the Schiff base condensation of formyltetrathiafulvalene and 2-aminopyridine. The preparation, X-ray crystal structure, electrochemical and magnetic characterization of a 1: 1 copper complex [Cu-II(hfac)(2)(TTF-CH=N-Py)] (2) are reported. The crystal structure reveals that the imine N atom participates in chelation to the paramagnetic center, thus making this ligand an attractive precursor for the assembly of pi-d systems.

  DOI：

  10.1021/ic062257p