tris{2-(2'-hydroxy-5'-isopropylbenzylideneamino)ethyl}amine | 137460-52-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: tris{2-(2'-hydroxy-5'-isopropylbenzylideneamino)ethyl}amine
• CAS: 137460-52-7
• 化学式: C₃₆H₄₈N₄O₃
• 分子量: 584.802
• InChiKey: HQAPPHKCEVUNGB-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  galium(III) nitrate monohydrate 、 tris{2-(2'-hydroxy-5'-isopropylbenzylideneamino)ethyl}amine 在 sodium acetate 作用下， 以 乙醇 为溶剂， 以61%的产率得到gallium-tris{(2-hydroxy-5-isopropyl-benzylidenimino)ethyl}amine
  参考文献：
  名称：

  Synthesis, stereochemical characterisation and absolute configuration of enantiomerically pure complexes of sexidentate ligands

  摘要：

  The optically active sexidentate Schiff bases [H3L5] and [H3L6] were prepared from tris[(S)-2-aminopropyl]amine and 5-chlor- and 5-isopropylsalicylaldehyde, respectively. Reaction of rhodium trichloride with [H3L6] gave an enantiomerically pure [RhL6] complex with an absolute configuration of LAMBDA-for the octahedral arrangement. The chiroptical properties are given.

  DOI：

  10.1007/bf00809812

文献信息

• Hunter, Geoffrey; Kilcullen, Neil, Journal of the Chemical Society, Dalton Transactions
  作者：Hunter, Geoffrey、Kilcullen, Neil

  DOI：——

  日期：——