| 1515880-97-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• CAS: 1515880-97-3
• 化学式: C₂₆H₃₄FNOPPd*I
• 分子量: 659.859
• InChiKey: UONJFQQAKILJQX-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  对氟碘苯 、 ditert-butyl-[(Z)-(8-ethoxyquinolin-1-id-2-ylidene)methyl]phosphane;fluorobenzene;palladium(2+) 在 乙硫醇 、 sodium t-butanolate 作用下， 以 苯 为溶剂， 反应 2.0h， 生成
  参考文献：
  名称：

  Room Temperature Rapid Functionalization of E–H Bonds (E = O, N, S) via the Metal–Ligand Cooperation Mechanism

  摘要：

  An arylpalladium PNF-type pincer complex reacts with water and anilines under very mild conditions, providing access to new PNO- and PNN-pincer complexes with concomitant hydrogen transfer to the ligand core. Such a metal-ligand cooperation mode allows for the irreversible double activation of even highly sterically hindered aniline molecules. With thiols, the activation mode depends on the nature of the substituent at the sulfur atom, with thiophenols giving products of C-S elimination.

  DOI：

  10.1021/ic402315a