(4aS,6aS,6bR,8aR,9R,10R,11R,12aR,12bR,14bS)-10-Acetoxy-11-methoxy-9-methoxymethyl-2,2,6a,6b,9,12a-hexamethyl-1,3,4,5,6,6a,6b,7,8,8a,9,10,11,12,12a,12b,13,14b-octadecahydro-2H-picene-4a-carboxylic acid methyl ester | 139877-38-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (4aS,6aS,6bR,8aR,9R,10R,11R,12aR,12bR,14bS)-10-Acetoxy-11-methoxy-9-methoxymethyl-2,2,6a,6b,9,12a-hexamethyl-1,3,4,5,6,6a,6b,7,8,8a,9,10,11,12,12a,12b,13,14b-octadecahydro-2H-picene-4a-carboxylic acid methyl ester
• CAS: 139877-38-6
• 化学式: C₃₅H₅₆O₆
• 分子量: 572.826
• InChiKey: LWAJXFYPJXWYDZ-KFAXLXDNSA-N

反应信息

• 作为产物：
  描述：

  在 吡啶 、 盐酸 作用下， 反应 4.0h， 生成 (4aS,6aS,6bR,8aR,9R,10R,11R,12aR,12bR,14bS)-10-Acetoxy-11-methoxy-9-methoxymethyl-2,2,6a,6b,9,12a-hexamethyl-1,3,4,5,6,6a,6b,7,8,8a,9,10,11,12,12a,12b,13,14b-octadecahydro-2H-picene-4a-carboxylic acid methyl ester
  参考文献：
  名称：

  Arjunolitin, a triterpene glycoside fromTerminalia arjuna

  摘要：

  Arjunolic acid diglycoside, which we have named arjunolitin, has earlier been reported from Terminalia arjuna. Its structure has now been established as 3-O-beta-D-glycopyranosyl 2-alpha,3-beta,23-tri-hydroxyolean-12-en-28-oic acid 28-O-beta-D-glucopyranoside by chemical and spectral data.

  DOI：

  10.1016/0031-9422(91)83075-v