p-menth-4(8)-en-3-one-(2,4-dinitro-phenylhydrazone) | 2553-62-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: p-menth-4(8)-en-3-one-(2,4-dinitro-phenylhydrazone)
• 英文别名: (+/-)-Pulegon-<2,4-dinitro-phenylhydrazon>；p-Menth-4(8)-en-3-on-(2,4-dinitro-phenylhydrazon)；Pulegon-2.4-dinitrophenylhydrazon
• CAS: 2553-62-0
• 化学式: C₁₆H₂₀N₄O₄
• 分子量: 332.359
• InChiKey: NEVYZZPQFJKLCG-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  p-menth-4(8)-en-3-one-(2,4-dinitro-phenylhydrazone) 在 氧气 nitric oxide 作用下， 以 二氯甲烷 为溶剂， 反应 16.0h， 以96%的产率得到
  参考文献：
  名称：

  Stereoselective nitration of asymmetric hydrazones with nitric oxide

  摘要：

  Nitration of asymmetric hydrazones with nitric oxide occurred stereoselectively at C1'-atom, giving mono-nitrated trans isomer as a major outcome. The ratio of trans to cis was up to >99. Higher isolated yields of nitrated products and higher trans/cis ratios of isomers suggest that this procedure offers advantages for synthesizing asymmetry nitro compounds. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2007.09.128