[(benzo[h]quinoline(-H))Pd(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato(1-))] | 105693-87-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [(benzo[h]quinoline(-H))Pd(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato(1-))]
• 英文别名: [(benzo[h]quinoline)Pd(hexafluoroacetylacetonate)]；[(BzQ(-H))Pd(hexafluoroacetylacetonato)]
• CAS: 105693-87-6
• 化学式: C₁₈H₉F₆NO₂Pd
• 分子量: 491.685
• InChiKey: WWQXIPOJZFLTHZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  7,8-苯并喹啉 、 1,1,1,5,5,5-hexafluoro-2,4-pentanedione potassium salt 、 palladium diacetate 以 溶剂黄146 为溶剂， 生成 [(benzo[h]quinoline(-H))Pd(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato(1-))]
  参考文献：
  名称：

  Electrochemical and solvatochromic study of cyclopalladated complexes

  摘要：

  The electrochemistry and the optical absorption properties of a series of cyclopalladated complexes are reported. Variation of the cyclometallated ligand has been performed (azobenzene, 2-phenylpyridine and benzo[h]quinoline) as well as variation of the ancillary ligand (acetylacetone and hexafluoroacetylacetone). Results have confirmed that the LUMO energy levels of these complexes is mainly distributed on the cyclometallated ligand. High electronegativity of the fluorinated groups has a weak influence on the electrochemical and absorption properties of the complexes, except for the benzo[h]quinoline for which its planar and comparatively more aromatic character lead to a partial delocalisation of the LUMO energy level. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.cplett.2005.05.061