(1S,2S,7S)-2-(2-Furan-3-yl-2-oxo-ethyl)-7-methyl-3-methylene-9-oxa-tricyclo[5.3.3.0^1,6]tridecan-10-one | 85448-05-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (1S,2S,7S)-2-(2-Furan-3-yl-2-oxo-ethyl)-7-methyl-3-methylene-9-oxa-tricyclo[5.3.3.0^1,6]tridecan-10-one
• CAS: 85448-05-1
• 化学式: C₂₀H₂₄O₄
• 分子量: 328.408
• InChiKey: MMJRZYRMOZZOKA-YPDDKSJCSA-N

反应信息

• 作为产物：
  描述：

  2-((1S,5S,8aS)-5,8a-Bis-hydroxymethyl-5-methyl-2-methylene-decahydro-naphthalen-1-yl)-1-furan-3-yl-ethanone 生成 (1S,2S,7S)-2-(2-Furan-3-yl-2-oxo-ethyl)-7-methyl-3-methylene-9-oxa-tricyclo[5.3.3.0^1,6]tridecan-8-one 、 (1S,2S,7S)-2-(2-Furan-3-yl-2-oxo-ethyl)-7-methyl-3-methylene-9-oxa-tricyclo[5.3.3.0^1,6]tridecan-10-one
  参考文献：
  名称：

  THE STRUCTURE OF POTAMOGETONIN

  摘要：

  By conversion of methyl 15,16-epoxy-20-oxo-8(17),13(16),14 labdatrien-19-oate (3) into 15,16-epoxy-8(17),13(16),14-labdatrien-19,20-olide (1) and 15,16-epoxy-8(17),13(16),14-labdatrien-20,19-olide (8), the structure of potamogetonin was proved to be 15,16-epoxy-8(17),13(16),14-ent-labdatrien-20,19-olide (10), not 1 as proposed by Smith et al.

  DOI：

  10.1246/cl.1983.1