2-Allyloxymethyl-3,6-dioxa-1,8-octanediol | 271789-15-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: 2-Allyloxymethyl-3,6-dioxa-1,8-octanediol
• 英文别名: 2-[2-(2-hydroxyethoxy)ethoxy]-3-prop-2-enoxypropan-1-ol
• CAS: 271789-15-2
• 化学式: C₁₀H₂₀O₅
• 分子量: 220.266
• InChiKey: KVTXQTHLDRSGKY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.42
• 重原子数：
  15.0
• 可旋转键数：
  11.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  68.15
• 氢给体数：
  2.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  2-Allyloxymethyl-3,6-dioxa-1,8-octanediol 在 palladium on activated charcoal 4-二甲氨基吡啶 、 sodium hydride 、 caesium carbonate 、 三乙胺 作用下， 以 四氢呋喃 、 乙醇 、 二氯甲烷 、 乙腈 为溶剂， 反应 102.25h， 生成 25,27-Dimethoxy-p-tert-butylcalix[4]arene-26,28-[2-(2,2'-bipyridine-6-methyl)oxy-methyl]crown-4
  参考文献：
  名称：

  2,2′-Bipyridine Lariat Calixcrowns: A New Class of Encapsulating Ligands Forming Highly Luminescent Eu3+ and Tb3+ Complexes

  摘要：

  A new class of calix[4]arene crown ethers with one or two bipyridines appended to the polyether ring (lariat calixcrowns) have been designed and synthesized; the luminescence properties of their Eu3+ and Tb3- complexes have been studied in acetonitrile. In this solvent, long lifetimes for the metal emitting states and high metal-luminescence intensities obtained upon ligand excitation have been observed in both Eu3+ and Tb3+ complexes The association constants in methanol have been determined for some of the complexes studied.

  DOI：

  10.1002/(sici)1521-3765(20000317)6:6<1026::aid-chem1026>3.0.co;2-c
• 作为产物：
  描述：

  1-O-allyl-3-O-triphenylmethylglycerol 在 盐酸 、 甲醇 、 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 34.5h， 生成 2-Allyloxymethyl-3,6-dioxa-1,8-octanediol
  参考文献：
  名称：

  2,2′-Bipyridine Lariat Calixcrowns: A New Class of Encapsulating Ligands Forming Highly Luminescent Eu3+ and Tb3+ Complexes

  摘要：

  A new class of calix[4]arene crown ethers with one or two bipyridines appended to the polyether ring (lariat calixcrowns) have been designed and synthesized; the luminescence properties of their Eu3+ and Tb3- complexes have been studied in acetonitrile. In this solvent, long lifetimes for the metal emitting states and high metal-luminescence intensities obtained upon ligand excitation have been observed in both Eu3+ and Tb3+ complexes The association constants in methanol have been determined for some of the complexes studied.

  DOI：

  10.1002/(sici)1521-3765(20000317)6:6<1026::aid-chem1026>3.0.co;2-c

文献信息

• CHEN, YUANYIN;LUO, JIEQI;LU, XUCRAN, INYUN XUASYUEH, 6,(1989) N, S. 16-21
  作者：CHEN, YUANYIN、LUO, JIEQI、LU, XUCRAN

  DOI：——

  日期：——